Chemical apparatus; Electroplating; Glass blowing and working; Glass coatings; Glass grinding and polishing; Lampwork; Mirrors
For every 100 c.c. of plating solution about 7 grms. of dry
crystallised silver nitrate are required. The equivalent amount of
potassium cyanide (if dry and pure) is 5.2 grms, but commercial
cyanide may contain from 50 per cent upwards to 96 per cent in the
best fused cyanide made from ferrocyanide only. An approximate idea
of the cyanide content can be obtained from the dealers when the salt
is purchased, and this is all that is required.
A quantity slightly in excess of the computed amount of cyanide is
dissolved in distilled water, and this is cautiously added to the
solution of the silver nitrate till precipitation is just complete.
The supernatant liquors are then drained away, and the precipitate
dissolved by adding a sufficiency of the remaining cyanide; this
process is assisted by warming and stirring.
An allowance of about one-tenth of the whole cyanide employed may be
added to form "free" cyanide, and the solution made up to the strength
named. It is advisable to begin with the cyanide in a moderately
strong solution, for the sake of ease in dissolving the precipitate.
This solution will deposit silver upon articles of copper or brass
immersed in it even without the battery, but the coat will be thin.
The solution is used cold, with a current density of about 10 to 20
amperes per square foot. The articles to be silvered are
scratch-brushed, washed, and electroplated, till they begin to look
undesirably rough. They are then taken out of the bath, rebrushed,
and the process continued till a sufficiency of silver is deposited.
Four grammes weight of silver (nearly) is deposited per ampere hour.
It is best to use a fine silver anode, so that the solution, does not
get contaminated by copper.
In most factories it is usual to "quicken" the objects to be silvered
before placing them in the electrolysis vats, because the deposit is
said to adhere better in consequence of this treatment. I have never
found it any improvement for laboratory purposes, but it is easy to
do. A dilute (say 2 per cent) solution of cyanide of mercury is
required containing a little free cyanide. The objects to be
"quickened" are scratch-brushed and dipped into the cyanide of mercury
solution till they are uniformly white; it is generally agreed that
the less the mercury deposited the better, so long as a perfect
coating is obtained. The objects are rinsed after quickening, and put
in the depositing bath at once.
The mat surface of silver obtained by electrolysis of the cyanide is
very beautiful--one of the most beautiful things in nature--shining
with incomparable crystalline whiteness. So delicate is it, however,
for so great is the surface it exposes, that it is generally rapidly
deteriorated by exposure to the air. It may be protected to some
extent by lacquering with pale lacquer, but it loses some of its
brilliancy and purity in the process. The deposit is generally
scratch-brushed or burnished down to a regular reflecting surface.
Public-domain text, read in full here on John Shaqi.
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