Chemical apparatus; Electroplating; Glass blowing and working; Glass coatings; Glass grinding and polishing; Lampwork; Mirrors
It is therefore a good plan to keep a rough profit and loss account of
the gold in order to find the quantity in solution. Fifty dwts. per
gallon (or 78 grms. per 4.5 litres) is recommended. A gallon of
solution of this strength is worth about eleven pounds sterling in
gold and cyanide, and a serviceable anode will be worth about 10
pounds. (Fine gold is worth nominally four pounds four shillings and
eleven pence ha'penny per oz.) Gold may be easily obtained containing
less impurity than one part in ten thousand.
Sec. 137. Plating with Copper.
Copper may be deposited from almost any of its salts in reguline form,
the sulphate and nitrate being most usually employed. In the
laboratory a nearly saturated solution of sulphate of copper with 1 or
2 per cent of sulphuric acid will answer most purposes. A current
density of, at most, fifteen amperes per square foot may be used,
either for obtaining solid deposits for constructional purposes or for
calibrating current measuring instruments by electrolysis. A copper
anode is of course employed.
When coppering with a view to obtaining thick deposits it is a good
plan to place the electrodes several inches apart, and, if possible,
to keep the liquid stirred, as there is a considerable tendency on the
part of copper deposits to grow out into mossy masses wherever the
current density exceeds the limit mentioned. As the masses grow
towards the anode the defect naturally tends to increase of itself,
hence the necessity for care. The phenomenon is particularly marked
at the edges and corners of the cathode.
If the deposit becomes markedly irregular, the best plan is to stop
the process and file the face of the deposit down to approximate
smoothness. In coppering it is of the utmost importance that the
cathode be clean and free from grease; it must never be touched (by
the finger, for instance) from the time it is scratch-brushed till it
is immersed in the plating bath. Any grease or oxidation tends to
prevent the copper deposit adhering properly.
A copper deposit oxidises very easily when exposed to the air.
Consequently if the surface be required free from oxide, as, for
instance, when it is to be silvered or gilt, it must be quickly washed
when withdrawn from the coppering bath, scratch-brushed, and
transferred immediately to the silvering or gilding bath.
If the surface is to be dried, as in electrolysis calibrations, it
must be rinsed quickly with boiling water and pressed between sheets
of filter paper. Another method which has been recommended is to
rinse the copper in--water slightly acidulated with sulphuric acid
(which prevents oxidation), then in distilled water, and to dry by
blotting paper and in front of a fire, taking care not to make the
plate too hot. The wash water is sufficiently acidulated by the
addition of two or three drops of acid per litre. So far as I know,
the method of washing in acidulated water was first proposed by Mr. T.
Gray.
Public-domain text, read in full here on John Shaqi.
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