Chemical apparatus; Electroplating; Glass blowing and working; Glass coatings; Glass grinding and polishing; Lampwork; Mirrors
I do not propose to deal with the subject of electrotyping to any
extent, for if practised as an art, a good many little precautions are
required, as the student may read in Gore's Electro-metallurgy. The
above instructions will be found sufficient for the occasional use of
the process in the construction of apparatus, etc. There is no
advantage in attempting to hurry the process, a current density of
about ten amperes per square foot being quite suitable and
sufficiently low to ensure a solid deposit.
Sec. 143. Blacking Brass Surfaces.
A really uniform dead-black surface is difficult to produce on brass
by chemical means. A paste of nitrate of copper and nitrate of silver
heated on the brass is said to give a dead-black surface, but I have
not succeeded in making it act uniformly. For optical purposes the
best plan is to use a paint made up of "drop" black, ground very fine
with a little shellac varnish, and diluted for use with alcohol. No
more varnish than is necessary to cause the black to hold together
should be employed.
In general, if the paint be ground to the consistency of very thick
cream with ordinary shellac varnish it will be found to work well when
reduced by alcohol to a free painting consistency.
A very fine gray and black finish, with a rather metallic lustre, may
be easily given to brass work. For this purpose a dilute solution of
platinum tetrachloride (not stronger than 1 per cent) is prepared by
dissolving the salt in distilled water. The polished brass work is
cleaned by rubbing with a cork and strong potash till all grease has
disappeared, as shown by water standing uniformly on the metal and
draining away without gathering into drops.
After copious washing the work is wholly immersed in a considerable
volume of the platinum tetrachloride solution at the ordinary
temperature. After about a quarter of an hour the brass may be taken
out and washed. The surface will be found to be nicely and uniformly
coated if the above instructions have been carried out, but any
finger-marks or otherwise dirty places will cause irregularity of
deposit. If the process has been successful it will be found that the
deposit adheres perfectly, hardly any of it being removed by vigorous
rubbing with a cloth. If the deposit is allowed to thicken--either
by leaving the articles in the solution too long or heating the
solution, or having it too strong--it will merely rub off and leave
an irregular surface.
This process succeeds well with yellow brass and Muntz metal, either
cast or rolled, but it does not give quite such uniform (though still
good) results with gun-metal, on which, however, the deposit is darker
and deader in appearance.
A book might be written (several have been written) on the art of
metal colouring, but though doubtless a beautiful and delicate art, it
is of little service in the laboratory. For further information the
reader may consult a work by Hiorns.
Sec. 144. Sieves.
Public-domain text, read in full here on John Shaqi.
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