Chemical apparatus; Electroplating; Glass blowing and working; Glass coatings; Glass grinding and polishing; Lampwork; Mirrors
IN the Philosophical Magazine for July 1888 (vol. xxvi. p. 1) there
is a paper by Professor Kundt translated from the Sitzungsberichte of
the Prussian Academy. This paper deals with the indices of refraction
of metals. Thin prisms were obtained by depositing metals
electrolytically on glass surfaces coated with platinum. The
preparation of these surfaces is troublesome. Kundt recounts that no
less than two thousand trials were made before success was attained.
A detailed account of the preparation of these surfaces is not given
by Kundt, but one is promised--a promise unfortunately unfulfilled so
far as I am able to discover. A hunt through the literature led to
the discovery of the following references: Central Zeitung fuer Optik
und Mechanik, p. 142 (1888); Dingler's Polytechnik Journal, Vol.
cxcv. p. 464; Comptes Rendus, vol. lxx. (1870).
The original communication is a paper by Jouglet in the Comptes
Rendus, of which the other references are abstracts. The account in
Dingier is a literal translation of the original paper, and the note
in the Central Zeitung is abbreviated sufficiently to be of no value.
The details are briefly as follows:-
One hundred grams of platinum are dissolved in aqua regia and the
solution is dried on the sand bath, without, however, producing
decomposition. Though the instructions are not definite, I presume
that the formation of PtCl4 is contemplated.
The dried salt is added little by little to rectified oil of lavender,
placed on a glass paint-grinding plate, and the salt and oil are
ground together with a muller. Care is required to prevent any
appreciable rise of temperature which would decompose the compound
aimed at, and it is for this reason that the salt is to be added
gradually. Of course the absorption of water from the air must be
prevented from taking place as far as possible. Finally, the compound
is diluted by adding oil of lavender up to a total weight of 1400
grams (of oil).
The liquid is poured into a porcelain dish and left absolutely at rest
for eight days. It is then decanted and filtered, left six days at
rest, and again decanted (if necessary). The liquid should have a
specific gravity of 5 deg. on the acid hydrometer. (If by this the Baume
scale is intended, the corresponding specific gravity would be 1.037.)
A second liquid is prepared by grinding up 25 grams of litharge with
25 grams of borate of lead and 8 to 10 grams of oil of lavender. The
grinding must be thoroughly carried out.
This liquid is to be added to the one first described, and the whole
well mixed. The resulting fluid constitutes the platinising liquid,
and is applied as follows:-
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account