Chemical apparatus; Electroplating; Glass blowing and working; Glass coatings; Glass grinding and polishing; Lampwork; Mirrors
It is not a bad plan to get the glass exceedingly fluid round the
wire--even if the lump has to be blown out a little afterwards--as it
cools. The seal should finally be well annealed in asbestos, but
first by gradually moving it into the hot air in front of the flame.
It was observed by Professor J. J. Thomson and the author some years
ago (Proc. Roy. Soc. 40. 331. 1886) that when very violent
discharges are taken through lightly sealed-in electrodes in
lead-glass tubes--say from a large battery of Leyden jars--gas
appears to be carried into the tube over and above that naturally
given off by the platinum, and this without there being any apparent
want of perfection in the seal. This observation has since been
confirmed by others. Consequently in experiments on violent
discharges in vacuo where certainty is required as to the exclusion of
air, the seals should be protected by a guard tube or cap containing
mercury; this must, of course, be put in hot and clean, on hot and
clean glass, and in special cases should be boiled in situ.
A well-known German physicist (Warburg, I think) recommends putting
the seals under water, but I cannot think that this is a good plan,
for if air can get in, why not water? which has its surface tension
in its favour. The same reasoning prevents my recommending a layer of
sulphuric acid above the mercury-a method used for securing
air-tightness in "mercury joints" by Mr. Gimingham, Proc. R. S.
1874.
Further protection may be attained for many purposes by coating the
platinum wire with a sheath of glass, say half an inch long, fused to
the platinum wire to a depth of one-twentieth of an inch all round.
In some cases the electrodes must be expected to get very hot, for
instance, when it is desired to platinise mirrors by the device of
Professor Wright of Yale. In this and similar cases I have met with
great success by using "barometer" tubes of about one-twelfth of an
inch bore, and with walls, say, one-tenth of an inch thick.
[Footnote: "Barometer" tube is merely very thick-walled glass tubing,
and makes particularly bad barometers, which are sold as weather
glasses.]
This tube is drawn down to a long point--say an inch long by
one-eighth of an inch external diameter, and the wire is fused in for
a length, say, of three-quarters of an inch, but only in the narrow
drawn--down part of the tube. At different times I have tried four
such seals, and though the electrodes were red hot for hours, I have
never had an accident--of course they were well annealed.
Fig. 37.
For directions as to the making of high vacuum tubes, see the section
dealing with that matter.
Public-domain text, read in full here on John Shaqi.
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