Chemical apparatus; Electroplating; Glass blowing and working; Glass coatings; Glass grinding and polishing; Lampwork; Mirrors
For many purposes a cement is required capable of resisting carbon
bisulphide. This is easily made by adding a little treacle (say 20
per cent) to ordinary glue. Since the mixture of glue and treacle
does not keep, i.e. it cannot be satisfactorily melted up again after
once it has set, no more should be made up than will be wanted at the
time. If the glue be thick, glass boxes for carbon disulphide may be
easily put together, even though the edges of the glass strips are not
quite smooth, for, unlike most cements, this mixture remains tough,
and is fairly strong in itself.
I have found by experiment that most fixed and, to a less degree,
essential oils have little or no solvent action on shellac, and I
suspect that the same remark applies to the treacle-glue mixture, but
I have not tried. Turpenes act on shellac slightly, but mineral oils
apparently not at all. The tests on which these statements are based
were continued for about two years, during which time kerosene and
mineral oils had no observable effect on shellac--fastened
galvanometer mirrors.
Sec. 49. Fusing Electrodes into Glass.
This art has greatly improved since the introduction of the
incandescent lamp; however, up to the present, platinum seems to
remain the only substance capable of giving a certainly air-tight
result. I have not tried the aluminium-alumina method.
Many years ago it was the fashion to surround the platinum wire with a
drop of white enamel glass in order to cause better adhesion between
it and the ordinary glass. [Footnote: Hittorf and Geissler (Pogg.
Ann. 1864, Sec. 35; English translation, Phys. Soc. London, p. 138)
found that it was impossible to make air-tight joints between platinum
and hard potash glass, but that soft lead glass could be used with
success as a cement.] However, in the case of flint glass, if one may
judge from incandescent lamps, this is not essential--a fact which
entirely coincides with my own experience.
On the other hand, when sealing electrodes into German glass I have
often used a drop of enamel with perfect results, though this is not
always done in Germany. In all cases, however, in which electrodes
have to be sealed in--especially when they are liable to heat--I
recommend flint glass, and in this have the support of Mr. Rain (The
Incandescent Lamp and its Manufacture, p. 131). The exact details
for the preparation of eudiometer tubes are given by Faraday (Chemical
Manipulation, Sec. 1200).
In view of what has preceded, however, I will content myself with the
following notes. Make the hole through which the wire is to protrude
only slightly larger than the wire itself, and be sure that the latter
is clean. Allow the glass to cool sufficiently not to stick to the
wire when the latter is pushed in. Be sure that, on heating, the
glass does not get reduced, and that it flows up to the wire all
round; pull and push the wire a little with a pair of pincers, to
ensure this.
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