Chemical apparatus; Electroplating; Glass blowing and working; Glass coatings; Glass grinding and polishing; Lampwork; Mirrors
Surely in face of these facts we must admit that cement joints can be
made with fair success. I do not know the composition of M.
Regnault's mastic, but Faraday (Manipulations, Sec. 1123) gives the
following receipt for a cement for joining ferules to retorts, etc:
Resin 5 parts.
Beeswax 1 part.
Red ochre or Venetian red,
finely powdered and sifted 1 part.
I believe this to be substantially the same as Regnault's mastic,
though I have never analysed the latter.
For chemical work the possibility of evolution of gas from such a
cement must be taken into account, and I should certainly not trust it
for this reason in vacuum tube work, where the purity of the confined
gas could come in question. Otherwise it is an excellent cement, and
does not in my experience tend to crack away from glass to the same
extent as paraffin or pure shellac.
This cracking away from glass, by the way, is probably an effect of
difference in rate of expansion between the glass and cement which
probably always exists, and, if the cement be not sufficiently
viscous, must, beyond certain temperature limits, either produce
cracks or cause separation. Professor Wright of Yale has used a hard
mineral pitch as a cement in vacuum work with success.
My attention has been directed to a fusible metal cement containing
mercury, and made according to the following receipt, given by Mr. S.
G. Rawson, Journal of the Society of Chemical Industry, vol. ix.
(1890), P. 150:-
Bismuth 40 per cent
Lead 25 per cent
Tin 10 per cent
Cadmium 10 per cent
Mercury 15 per cent
This is practically one form of Rose's fusible metal with 15 per cent
mercury added. It takes nearly an hour to set completely, and the
apparatus must be clean and warm before it is applied.
As the result of several trials by myself and friends, I am afraid I
must dissent from the claim of the author that such a cement will make
a really air-tight joint between glass tubes. Indeed, the appearance
of the surface as viewed through the glass is not such as to give any
confidence, no matter what care may have been exercised in performing
all the operations and cleaning the glass; besides which the cement
is rigid when cold, and the expansion difficulty comes in.
On the other hand, if extreme air-tightness is not an object, the
cement is strong and easily applied, and has many uses. I have an
idea that if the joints were covered with a layer of soft wax, the
result would be satisfactory in so far as air-tightness is concerned.
This anticipation has since been verified.
Public-domain text, read in full here on John Shaqi.
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