On Molecular and Microscopic Science, Volume 1 (of 2)Somerville, Mary
History
On Molecular and Microscopic Science, Volume 1 (of 2)
Somerville, Mary
Matter -- Constitution; Microscopy; Natural history
Of all the spectra that have been determined, those of sodium and iron
are the most important and interesting. In that of sodium, the only
light is of the purest yellow condensed into a double line of intense
brilliancy on a dark ground. The iron spectrum on the contrary is
crossed by bright lines of all intensities and colours in such
multitudes, that their number has not been ascertained. The calcium
spectrum has one very bright green band in the orange, a red line in the
yellow, and a well-defined yellow line in the indigo. As already
mentioned, the red and orange parts of the strontium are crossed by many
red lines separated by dark intervals; there is a bright blue line
between the orange and yellow, and an orange line in the blue. One
intense crimson band in the orange characterises the lithium spectrum.
Seven broad green bands stripe the yellow and a part of the green, in
the barium spectrum, and that of magnesium has many green bands and
lines.
All of these were determined by the heat of white coal gas flame, which
amounts to 2350° Cent., and at the time MM. Bunsen and Kirchhoff were
not aware that by an increase of temperature new bright lines were added
to some of the spectra. That discovery was made by Professor Tyndall,
while examining the spectrum of chloride of lithium, which with the low
temperature has only one crimson band in the orange, but with the hotter
flame of hydrogen gas, amounting to 3259° Cent., an orange line appeared
in the yellow, and when Mr. Tyndall employed the electric lamp,[18] the
spectrum acquired a broad brilliant blue band between the orange and
yellow, while the crimson band remained unchanged. Professors Roscoe and
Clifton confirmed Tyndall’s discovery, and upon comparing the spectra of
strontium and lithium, they found where only one prism was employed that
the blue line of lithium appeared to coincide with the blue line, delta,
of strontium; but with an apparatus having several prisms like that of
Kirchhoff, they saw that the two blue lines differed by one division of
the measuring scale, the lithium line being the most refrangible. A
great change was produced on the strontium spectrum by increased
electric temperature: three of the red bands vanished, and new bright
lines appeared, that were not coincident with those they replaced; the
blue line was not affected, but four new violet lines were added. With
the intense heat of the electric spark, the broad green band of the
calcium spectrum is replaced by five green lines of less refrangibility,
the well-defined yellow line vanishes, and instead of the red band three
red or orange lines appear, of greater refrangibility than those that
have vanished. Six of the bright green bands in the spectrum of barium
entirely vanish, and bright new non-coincident lines appear. Thus, not
only new lines appear at very high temperature, but the broad bands,
characteristic of the metal or metallic compound at a low temperature of
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