On Molecular and Microscopic Science, Volume 1 (of 2)Somerville, Mary
History
On Molecular and Microscopic Science, Volume 1 (of 2)
Somerville, Mary
Matter -- Constitution; Microscopy; Natural history
The experiments of the Rev. Dr. Robinson on a variety of gases and
vapours, inclosed in glass tubes, show that a greater change is produced
by pressure than by heat. At the ordinary atmospheric pressure, the
spectra show a number of bright lines on a coloured ground, the light of
which is, in general, stronger towards the red than the violet end, and
strongest in the green. In some the ground is so bright as to efface all
but the most luminous lines. This is especially the case with hydrogen.
On gradually exhausting the tube in which the vapour is contained, the
spectra rather suddenly fade away, leaving only a suspicion of one or
two lines, but upon exhausting the tube still more, these transition
spectra become bright again, fresh lines appear, and they are changed
into new spectra which are never so bright as those at ordinary
pressure. Fewer lines are visible in the rarefied spectra, and of these
four-tenths are not found in the spectra of atmospheric pressure. The
difference between the common pressure spectra, the transition, and the
rarefied spectra shows, that the character and even the existence of
certain lines depend upon the mere density of the media, the chemical
circumstances remaining unchanged. Dr. Robinson also observed that
spectra are not superposed without a change; the spectrum of atmospheric
air does not always exhibit all the lines of oxygen and nitrogen, and
occasionally there are some lines not visible in either of them. It
appears also that for certain lines the actions of bodies may be
antagonistic.
Metals do not always give the same spectrum, whatever may be the
combinations in which they are found. Among various instances M.
Mitscherlich mentions that the spectra of copper and the chloride and
iodide of copper present essential differences, and Mr. Roscoe has found
that a similar difference prevails in the spectra of carbon compounds
when in a state of incandescent gas, which have hitherto been supposed
to yield the same spectrum. ‘The spectrum obtained from the flame of
olefiant gas is different from that obtained by the electric discharge
through a vacuum of the same gas; while the spark passing through a
cyanogen vacuum produces a spectrum identical with that of the olefiant
gas flame, and through the carbonic oxide vacuum a spectrum coincident
with that of the spark through olefiant gas vacuum.’
The chlorides, bromides, and iodides are the most easily vaporized of
all the metallic salts, and give the most brilliant flames and the most
intense spectra, especially the chlorides. A small piece of the chloride
of barium volatilized by a colourless gas flame tinges the flame green,
and the red and green lines on the spectrum stand out with extreme
brilliancy. The scattered yellow light on the spectrum of the chloride
of sodium is comparatively dark by contrast with the bright lines, and
upon shading off the more luminous part of it, traces of lines are
visible in the more refrangible portion.
Public-domain text, read in full here on John Shaqi.
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