On Molecular and Microscopic Science, Volume 1 (of 2)Somerville, Mary
History
On Molecular and Microscopic Science, Volume 1 (of 2)
Somerville, Mary
Matter -- Constitution; Microscopy; Natural history
Rosaniline or roseine, a white substance, is the base of aniline. It is
a powerful alkali, readily combining with acids to form highly coloured
salts, many of which have a tendency to crystallize, like magenta. This
base is most easily extracted from the acetate of aniline. The boiling
solution of that salt decomposed by a large excess of ammonia, yields a
crystalline precipitate of a reddish colour, and when the colourless
liquid is separated by filtration from the precipitate, it deposits on
cooling perfectly white needles and tablets of pure rosaniline. This
substance unites to acids in three different proportions forming three
kinds of salts. The salts that contain one equivalent of acid are
extremely stable compounds; for the most part they have a green metallic
reflection like some insects’ wings; by transmitted light they are red,
and their solutions in alcohol have the magnificent crimson colour of
magenta.
A bright purple dye is furnished by mixing equal weights of magenta and
aniline. When this mixture is kept at the temperature of 329° for some
hours and then mixed with water and hydrochloric acid to remove any
excess of magenta or aniline, the result is an insoluble purple residuum
or precipitate, but which when well washed with water becomes soluble in
alcohol and boiling water slightly acidulated with acetic acid. When the
insoluble purple residue is boiled several times with dilute
hydrochloric acid, a fine blue dye is formed; azuline, the most
beautiful of the blue dyes, which resists the action of the strongest
acids, and which is produced by oxidizing aniline under high pressure.
It was first prepared at Lyons from phenic acid, a product of the
distillation of coal; when pure it appears under the form of copper
bronze-coloured crystals soluble in alcohol, to which they communicate a
magnificent blue colour tinged with red; but most of the blue dyes are
derived from carbolic acid and from creosote. A blood-red colour is the
direct result of mixing the muriatic and phenic acids. Aniline, the
great source of the coal tar colours, yields also a fine yellow. A vast
deal of talent has been employed in the research of colouring dyes both
at home and abroad, in which the manufacturers themselves have shown
great scientific knowledge.
Attempts have been unsuccessfully made to obtain a green dye from
chlorophyll, the green colouring matter of plants. The want was for a
short time supplied by Lo-hao, a Chinese dye, but being unstable it was
given up. However the very same substance has been procured from the
Rhamnus cathartica (Buckthorn), one of the commonest European trees. M.
Charwin of Lyons, who made the discovery, has utilized a waste
substance, and rendered it permanent as a dye. It is the only known
substance which with proper reagents is capable of producing all the
seven colours of the spectrum.[14]
Public-domain text, read in full here on John Shaqi.
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