On the Connexion of the Physical SciencesSomerville, Mary
Science
On the Connexion of the Physical Sciences
Somerville, Mary
Physical sciences; Science
direction of the strongest, and exactly the same with that which a third
plate would produce equal in thickness to the difference of the two.
M. Biot has discovered the same properties in a variety of liquids. Oil
of turpentine, and an essential oil of laurel, cause the plane of
polarization to turn to the left, whereas the syrup of sugar-cane, and a
solution of natural camphor, by alcohol, turn it to the right. A
compensation is effected by the superposition or mixture of two liquids
which possess these opposite properties, provided no chemical action
takes place. A remarkable difference was also observed by M. Biot
between the action of the particles of the same substances when in a
liquid or solid state. The syrup of grapes, for example, turns the plane
of polarization to the left as long as it remains liquid; but, as soon
as it acquires the solid form of sugar, it causes the plane of
polarization to revolve towards the right, a property which it retains
even when again dissolved. Instances occur also in which these
circumstances are reversed.
A ray of light passing through a liquid possessing the power of circular
polarization is not affected by mixing other fluids with the liquid—such
as water, ether, alcohol, &c.—which do not possess circular polarization
themselves, the angle of deviation remaining exactly the same as before
the mixture. Whence M. Biot infers that the action exercised by the
liquids in question does not depend upon their mass, but that it is a
molecular action exercised by the ultimate particles of matter, which
depends solely upon the individual constitution, and is entirely
independent of the positions and mutual distances of the particles with
regard to each other. These important discoveries show that circular
polarization surpasses the power of chemical analysis in giving certain
and direct evidence of the similarity or difference existing in the
molecular constitution of bodies, as well as of the permanency of that
constitution, or of the fluctuations to which it may be liable. For
example, no chemical difference has been discovered between syrup from
the sugar-cane and syrup from grapes. Yet the first causes the plane of
polarization to revolve to the right, and the other to the left;
therefore some essential difference must exist in the nature of their
ultimate molecules. The same difference is to be traced between the
juices of such plants as give sugar similar to that from the cane, and
those which give sugar like that obtained from grapes.
If chlorate of soda be dissolved in water, the liquid has no circular
polarization; but if the solution be allowed to crystallize, some of the
crystals turn the light to the right and others to the left. Now, if all
those of one kind be gathered together and dissolved a second time, the
liquid will have no circular polarization; but if crystals be allowed to
form, some will turn the light to the right and others to the left,
although only one kind was dissolved.[11]
Public-domain text, read in full here on John Shaqi.
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