On the Connexion of the Physical SciencesSomerville, Mary
Science
On the Connexion of the Physical Sciences
Somerville, Mary
Physical sciences; Science
Liquids, the various kinds of glass, and probably all substances,
whether solid or liquid, that do not crystallize regularly, are more
pervious to the calorific rays according as they possess a greater
refractive power. For example, the chloride of sulphur, which has a high
refractive power, transmits more of the calorific rays than the oils,
which have a less refractive power: oils transmit more radiant heat than
the acids; the acids more than aqueous solutions; and the latter more
than pure water, which of all the series has the least refractive power,
and is the least pervious to heat. M. Melloni observed also that each
ray of the solar spectrum follows the same law of action with that of
terrestrial rays having their origin in sources of different
temperatures; so that the very refrangible rays may be compared to the
heat emanating from a focus of high temperature, and the least
refrangible to the heat which comes from a source of low temperature.
Thus, if the calorific rays emerging from a prism be made to pass
through a layer of water contained between two plates of glass, it will
be found that these rays suffer a loss in passing through the liquid as
much greater as their refrangibility is less. The rays of heat that are
mixed with the blue or violet light pass in great abundance, while those
in the obscure part which follows the red light are almost totally
intercepted. The first, therefore, act like the heat of a lamp, and the
last like that of boiling water.
These circumstances explain the phenomena observed by several
philosophers with regard to the point of greatest heat in the solar
spectrum, which varies with the substance of the prism. Sir William
Herschel, who employed a prism of flint glass, found that point to be a
little beyond the red extremity of the spectrum; but, according to M.
Seebeck, it is found to be upon the yellow, upon the orange, on the red,
or at the dark limit of the red, according as the prism consists of
water, sulphuric acid, crown or flint glass. If it be recollected that,
in the spectrum from crown glass, the maximum heat is in the red part,
and that the solar rays, in traversing a mass of water, suffer losses
inversely as their refrangibility, it will be easy to understand the
reason of the phenomenon in question. The solar heat which comes to the
anterior face of the prism of water consists of rays of all degrees of
refrangibility. Now, the rays possessing the same index of refraction
with the red light suffer a greater loss in passing through the prism
than the rays possessing the refrangibility of the orange light, and the
latter lose less in their passage than the heat of the yellow. Thus the
losses, being inversely proportional to the degree of refrangibility of
each ray, cause the point of maximum heat to tend from the red towards
the violet, and therefore it rests upon the yellow part. The prism of
sulphuric acid, acting similarly, but with less energy than that of
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