On the Connexion of the Physical SciencesSomerville, Mary
Science
On the Connexion of the Physical Sciences
Somerville, Mary
Physical sciences; Science
An accumulation of heat invariably produces light: with the exception of
the gases, all bodies which can endure the requisite degree of heat
without decomposition begin to emit light at the same temperature; but,
when the quantity of heat is so great as to render the affinity of their
component particles less than their affinity for the oxygen of the
atmosphere, a chemical combination takes place with the oxygen, light
and heat are evolved, and fire is produced. Combustion—so essential for
our comfort, and even existence—takes place very easily from the small
affinity between the component parts of atmospheric air, the oxygen
being nearly in a free state; but, as the cohesive force of the
particles of different substances is very variable, different degrees of
heat are requisite to produce their combustion. The tendency of heat to
a state of equal diffusion or equilibrium, either by radiation or
contact, makes it necessary that the chemical combination which
occasions combustion should take place instantaneously; for, if the heat
were developed progressively, it would be dissipated by degrees, and
would never accumulate sufficiently to produce a temperature high enough
for the evolution of flame.
It is a general law that all bodies expand by heat and contract by cold.
The expansive force of heat has a constant tendency to overcome the
attraction of cohesion, and to separate the constituent particles of
solids and fluids; by this separation the attraction of aggregation is
more and more weakened, till at last it is entirely overcome, or even
changed into repulsion. By the continual addition of heat, solids may be
made to pass into liquids, and from liquids to the aëriform state, the
dilatation increasing with the temperature; and every substance expands
according to a law of its own. Gases expand more than liquids, and
liquids more than solids. The expansion of air is more than eight times
that of water, and the increase in the bulk of water is at least
forty-five times greater than that of iron. Metals dilate uniformly from
the freezing to the boiling points of the thermometer; the uniform
expansion of the gases extends between still wider limits; but, as
liquidity is a state of transition from the solid to the aëriform
condition, the equable dilatation of liquids has not so extensive a
range. This change of bulk, corresponding to the variation of heat, is
one of the most important of its effects, since it furnishes the means
of measuring relative temperature by the thermometer and pyrometer. The
rate of expansion of solids varies at their transition to liquidity, and
that of liquidity is no longer equable near their change to an aëriform
state. There are exceptions, however, to the general laws of expansion;
some liquids have a maximum density corresponding to a certain
temperature, and dilate whether that temperature be increased or
diminished. For example—water expands whether it be heated above or
cooled below 40°.
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