On the Connexion of the Physical SciencesSomerville, Mary
Science
On the Connexion of the Physical Sciences
Somerville, Mary
Physical sciences; Science
Mr. Grove considers that the colour of the voltaic arc, or flame, which
appears between the poles of a very powerful battery, depends upon the
substance of the metal from whence it proceeds and on the medium through
which it passes. The spark from zinc is blue, from silver it is green,
from iron it is red and scintillating—precisely the colours afforded by
these metals in their ordinary combustion. But the colour varies also
with the medium through which the light passes, for when the medium is
changed a change takes place in the colour, showing an affection of the
intervening matter. A portion of the metal terminals or poles is
actually transmitted with every electrical or Voltaic discharge, whence
Mr. Grove concludes that the electrical discharge arises, at least in
part, from an actual repulsion and severance of the electrified matter
itself, which flies off at the points of least resistance. He observes
that “the phenomena attending the electric spark or Voltaic arc tends to
modify considerably our previous idea of the nature of the electric
force as a producer of ignition and combustion. The Voltaic arc is
perhaps, strictly speaking, neither ignition nor combustion. It is not
simply ignition; because the matter of the terminals is not merely
brought to a state of incandescence, but is physically separated, and
partially transferred from one terminal to another, much of it being
dissipated in a vaporous state. It is not combustion; for the phenomena
will take place independently of atmospheric air, oxygen gas, or any of
the bodies usually called supporters of combustion; combustion being in
fact chemical union attended with heat and light. In the Voltaic arc we
may have no chemical union, for if the experiment be performed in an
exhausted receiver, or in nitrogen, the substance forming the terminals
is condensed and precipitated upon the interior of the vessel, in,
chemically speaking, an unaltered state. Thus, to take a very striking
example, if the Voltaic discharge be taken between zinc terminals in an
exhausted receiver, a fine black powder of zinc is deposited on the
sides of the receiver; this can be collected, and takes fire readily in
air by being touched with a match, or ignited wire, instantly burning
into white oxide of zinc. To an ordinary observer the zinc would appear
to be burned twice—first in the receiver, where the phenomenon presents
all the appearance of combustion, and, secondly, in the real combustion
in air. With iron the experiment is equally instructive. Iron is
volatilized by the Voltaic arc in nitrogen, or in an exhausted receiver;
and when a scarcely perceptible film has lined the receiver, if it be
washed with an acid, it then gives, with ferrocyanide of potassium, the
Prussian-blue precipitate. In this case we readily distil iron, a metal
by ordinary means _fusible_ only at a very high temperature.”
Public-domain text, read in full here on John Shaqi.
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