Paint Technology and TestsGardner, Henry A. (Henry Alfred)
Science
Paint Technology and Tests
Gardner, Henry A. (Henry Alfred)
Paint
=Barium Sulphate (Barytes).= By grinding the crude ore, treating with
acid to remove the iron, and finally washing, floating, and drying,
there is produced the commercial form of this valuable pigment. It is
used in large quantity as a base upon which to precipitate colors, and
also together with other white pigments in the manufacture of
ready-mixed paints. It renders the paint coating more resistant to
abrasion, and gives to the paint certain very important brushing
qualities. It is a very stable pigment, not being materially affected by
either acid or alkali, and can be used with the most delicate colors. In
oil it is transparent and must be mixed with opaque pigments when used
in ready-mixed paints. It is generally used with lighter pigments, such
as asbestine, in order to prevent settling. Under the microscope, both
by polarized and transmitted light, the sharp angles of the particles
appear distinctly, with no tendency to mass into a compact form.
Although transparent in oil, it is valuable in moderate percentage in a
ready-mixed paint.
=Barium Sulphate (Blanc Fixe).= Blanc fixe is the precipitated form of
barium sulphate, resulting from the action of soluble barium salts on
soluble sulphates. The specific gravity (4.2) of this compound is lower
than that of barytes. Possessing greater opacity in oil, it is of more
value as a paint pigment for some purposes. It comes in for its greatest
use as a base on which to precipitate lake colors. The very fine
particles show a slight tendency to agglomerate.
=Calcium Carbonate (Whiting).= The natural form of calcium carbonate,
prepared from chalk, has a much higher specific gravity (2.74) than that
of the artificial form (2.5) prepared by the precipitation of calcium
carbonate. The latter, however, possesses greater hiding properties.
Both grades find a wide use in distemper work and in the manufacture of
putty. It is often used in small percentage in many ready-mixed paints.
The photomicrograph of the pigment shows the presence of many large
particles.
=Calcium Sulphate (Gypsum).= The mineral gypsum, consisting of calcium
sulphate and about 21% of water of combination, is sometimes used as a
paint pigment after grinding and dehydration. Being slightly soluble in
water it has a tendency to pass into solution when exposed to
atmospheric agencies. It lacks hiding power in oil. Its specific gravity
is 2.3. As in the case of all pigments prepared directly from mineral
substances, the many-sized and shaped particles appear clearly when
enlarged. Partially and wholly dehydrated forms of gypsum are also used
in paint.
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