Paint Technology and TestsGardner, Henry A. (Henry Alfred)
Science
Paint Technology and Tests
Gardner, Henry A. (Henry Alfred)
Paint
By means of this machine it is possible to obtain very valuable
information concerning the effect of age upon a paint as influencing its
strength and elasticity. These are two vital qualities in a paint, as it
is through its strength that a paint resists abrasion, cracking,
peeling, and blistering. That elasticity is a vital qualification of a
paint may easily be seen through the checking of oil paintings, which,
as Ostwalt has pointed out, is due to the unequal coefficients of
expansion between the ground and the paint. This is particularly
noticeable in the alligatoring of many enamels which contain large
percentages of zinc.
Curves have been prepared having pressure as an abscissa and elasticity
as ordinate. These curves show remarkable differences in different
pigments. For instance, in the case of white lead, the curve takes a
steep upward trend when it apparently reaches a maximum, the curve then
flattening out and finally taking another steep upward trend just before
breaking. This may be construed as follows: That under low pressures the
white lead film is perfectly elastic, when a maximum is obtained, beyond
which elasticity does not extend. This point is the maximum point of the
upward trend. From here on pressure may be applied without any increase
in stretch, this being represented by the flat part of the curve, while
the steep upward trend just before breaking shows where the paint begins
to tear, finally culminating in breaking. In the case of asbestine,
however, the curve is more of a straight line up to the breaking point,
which would go to prove that elasticity is proportionate to pressure in
the case of this pigment.
=Moisture Absorption.= The structure of certain pigments is such that
when they are ground in linseed oil and painted out, films are produced
which are very water-resistant. This action is possibly due to the
filling of the voids in the oil, thus making a compact and
water-resistant film. Pigments which are coarse and which present an
angular crystalline structure, often produce films which contain a
relatively large number of voids and are less waterproof. Certain
pigments are chemically active and tend to produce, when ground in oil,
metallic soaps which act for a time more or less as varnish gums, in
keeping out moisture. Later on, however, such films are apt to break
down and admit moisture in quantity. The tests herein described were
designed by the author to determine the water-excluding value of a
number of typical pigments when ground in linseed oil and painted out
into films. Unfortunately, no method has been devised by which films of
the same gauge could be prepared. The variations in the thickness of the
films used in these experiments, however, are not very great.
[Illustration: Apparatus for Determining Excluding Properties of Paint
Films]
Public-domain text, read in full here on John Shaqi.
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