Paint Technology and TestsGardner, Henry A. (Henry Alfred)
Science
Paint Technology and Tests
Gardner, Henry A. (Henry Alfred)
Paint
A slide of paint containing these re-enforcing pigments is prepared in
the usual manner. On examining this under the microscope and using the
polarizing apparatus, the crystalline pigments are at once detected by
revolving the analyzer. At one position of the analyzer, one sees an
ordinary field, as with transmitted light, but if one revolves the
analyzer, the field gradually becomes darker until total darkness is
obtained throughout, except in such places where crystalline substances
are present, when the crystal is shown up with beautiful distinctness.
Photomicrographs of various single pigments and pigment combinations are
shown under Chapter III.
=Effect of Pigments on Oil.= Certain pigments have the property of
acting upon the linseed oil in which they are ground, forming metallic
linoleates which accelerate the drying of oil. This is especially true
of lead and zinc pigments. The inert crystalline pigments, when ground
in linseed oil and painted out, distribute the oil so as to allow a
great surface to be exposed to the air. Thus by physical action, and
possibly catalytic or contact action, these inert pigments stimulate the
drying of oil paints in which they are ground. Lead and zinc paints, of
course, have the greatest drying values on account of the added effect
of the linoleates formed, as outlined above. The writer has made a
series of tests in which the action of various pigments upon linseed oil
is shown. The tests were made in the following manner:
Five grams of each of a series of commonly used paint pigments,
including those of inert crystalline nature as well as the more valuable
amorphous pigments which are considered more or less chemically active,
were ground separately in an agate mortar, with 5 grams of raw linseed
oil. The ground paste in each case was placed in a marked glass beaker,
and allowed to stand in a dustless section of the laboratory for one
month. The oil-pigment paste from each beaker was then separately
extracted with benzine to remove the linseed oil from the pigment. The
benzine solutions of oil were then heated to remove the benzine and the
residue of oil burned to ash in crucibles. The ash from each test was
weighed, and if it ran above the percentage of ash determined on a blank
sample of linseed oil (namely, .003%), the ash was analyzed
qualitatively for metallic constituents. The following table of results
shows the percentage increase in ash, as well as the constituents of ash
on the various samples tested:
TABLE OF RESULTS
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