Pharmacologia: Fourth American, from the Seventh London EditionParis, John Ayrton
Science
Pharmacologia: Fourth American, from the Seventh London Edition
Paris, John Ayrton
Pharmacognosy; Pharmacology; Pharmacy
under that article. See _Acetum_. _Sulphurous Acid_ may be recognised by
drawing a little of the vapour into the lungs. The presence of _Nitric
Acid_ may be discovered by saturating the suspected sample with pure
potass, evaporating to dryness, and then treating the product with a
highly concentrated alcohol, the acetate of potass will be thus
dissolved, but as it exerts no action on the _Nitrate_ it will be found
in the residuum, and may be recognised by its deflagration, when thrown
upon burning charcoal;[332] _Copper_ may be detected by the acid
assuming a blue colour, when supersaturated with ammonia; and _Lead_, by
a solution of sulphuretted hydrogen, producing a dark coloured
precipitate. _Tin_ however is the metal with which distilled vinegar is
more usually contaminated, for no vegetable acid will act upon lead
while any tin is present in the mixture, since the latter, being more
oxidable than the former, is exclusively dissolved.
ACIDUM ACETICUM FORTIUS. L.
(_Acidum Aceticum._)
(_e Ligno Destillatum._)
_vulgo, Pyroligneous Acid._
The acetic acid from wood has been very generally introduced to
supersede the use of distilled vinegar for the purposes of Medicine and
the Arts.[333] It is at length found to be capable of such complete
separation from all foreign matter as to afford a perfectly pure acetic
acid, invariable in its acidifying power, and immutable in its chemical
properties. In justice to the skill and industry of Messrs. Beaufoy and
Co. of South Lambeth, I beg to state that I have examined various
specimens of this acid from their manufactory, and that I find it free
from those impurities which have hitherto constituted an insuperable
objection to its introduction into the Materia Medica. The purified
_Pyroligneous_ acid, manufactured by this company, and sold under the
name of “_Improved Distilled Vinegar_,” is perfectly free from any
unpleasant taste, as well as colour and sediment; and it forms a limpid
and colourless solution with ammonia. The common distilled vinegar of
the shops varies essentially in strength as well as purity, differing in
acidifying power from 30 to 40 per cent. in value: it is sometimes 7
degrees, and at others less than 5, by the Revenue Acetometer;[334] and
hence has arisen the difficulty of procuring an uniform article for
medical application, a difficulty which the introduction of the
_pyroligneous_ acid seems calculated to overcome, as it may be procured
from the manufacturers of any degree of concentration,[335] from 6
degrees of the Acetometer, or 2·826 per cent. of real acetic acid to 130
degrees, or 61·49 per cent. of acid; and even of still higher strength
if required; their common, or _Proof_ acid is about equivalent in
strength to that of the best Malt Vinegar, of which 100 grains will
saturate 14½ grains of crystallized _Sub-carbonate of Soda_, and
consequently contains 4·73 per cent.
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