=179. Heat Capacity of Water.=--The large capacity for heat shown by
water is useful in regulating the temperature of the air near lakes and
the ocean. In hot weather the water rises slowly in temperature
absorbing heat from the warm winds blowing over it. In winter the large
amount of heat stored in the water is slowly given out to the air above.
Thus the climate near the ocean is made more moderate both in winter and
summer by the large capacity of water for heat. This large heat capacity
of water may seem to be a disadvantage when one is warming it for
domestic purposes since it requires so much heat to warm water to
boiling. However, it is this capacity that makes hot-water bottles and
hot-water heating effective.
If one takes a pound of ice at 0°C. in one dish and a pound of
water at 0°C. in another, and warms the dish of ice by a Bunsen
flame until the ice is just melted, and then warms the water in the
other dish for the same time, the water will be found to be _hot_
and at a temperature 80°C., or 176°F.
=180. The Heat of Fusion of Ice.=--This experiment indicates the large
amount of heat required to change the ice to water without changing its
temperature. As indicated by the experiment, it requires 80 calories to
melt 1 g. of ice without changing its temperature or, in other words, if
one placed 1 g. of ice at 0°C. in 1 g. of water at 80°C., the ice would
be melted and the water would be cooled to 0°C.
=181. Heat Given out by Freezing water.=--Just as 80 calories of heat
are required to melt 1 g. of ice, so in freezing 1 g. of water, 80
calories of heat are given out.
The fact that heat is set free or given out when a liquid
solidifies may be strikingly shown by making a strong solution of
sodium acetate. On allowing this to cool quietly it will come to
the room temperature and remain liquid. If now a small crystal of
sodium acetate is dropped into the liquid the latter quickly
becomes a solid mass of crystals, at the same time rising markedly
in temperature. The amount of heat now liberated must enter the
sodium acetate when the mass of crystals is melted again.
The large amount of heat that must be liberated before water freezes
accounts for the slowness of the formation of ice. It is also the reason
why the temperature never falls so low in the vicinity of large lakes as
it does far inland, the heat given out by the freezing water warming the
surrounding air.
The heat that disappears on melting and reappears on solidifying is
called the _heat of fusion_. It is sometimes called _latent heat_ since
the heat seems to become hidden or latent. It is now believed that the
heat energy that disappears when a body melts has been transformed into
the _potential energy_ of partially separated molecules. The heat of
fusion therefore represents the work done in changing a solid to a
liquid without a change of temperature.
Public-domain text, read in full here on John Shaqi.
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