=188. Artificial Cooling.=--The fact has been brought out that when a
solid is melted, a certain amount of heat, called the heat of fusion, is
absorbed or disappears. This absorption of heat is also noticed when a
solid is liquefied by dissolving it in a liquid as well as when it is
liquefied by simply applying heat. Thus if some table salt is placed in
a tumbler of water the temperature of the solution is lowered several
degrees below that of the salt and water used. The liquefaction or
solution of the salt has been accompanied by an absorption or
disappearance of heat. This heat has been taken from the salt and from
the water, resulting in a lowered temperature. Sal ammoniac or ammonium
nitrate when dissolved in water produce a much more marked cooling
effect than does table salt. The dissolving of a crystal in a liquid is
something like evaporation, except that the molecules of the liquid
attract the molecules of the solid and thus assist the change of state.
=189. Freezing Mixtures.=--If one attempts to freeze a solution of salt
and water, ice will not form at 0°C. but several degrees lower. The ice
formed however is pure. Evidently the attraction of the molecules of
salt for the water molecules prevented the formation of ice until the
motions of the water molecules had been reduced more than is necessary
in pure water. As the temperature of freezing water is that of melting
ice, ice in a salt solution melts at lower temperature than in pure
water. In a saturated salt solution this temperature is -22°C. It is
for this reason that the mixture of ice and salt used in freezing cream
is so effective, the salt water in melting the ice, being cooled to a
temperature many degrees below the freezing point of the cream. The best
proportion for a freezing mixture of salt and ice is one part salt to
three parts of finely powdered or shaved ice.
=190. Refrigeration by Evaporation.=--Intense cold is also produced by
permitting the rapid evaporation of liquids under pressure. Carbon
dioxide under high pressure is a liquid, but when allowed to escape into
the air evaporates so rapidly that a portion of the liquid is frozen
into solid carbon dioxide which has a temperature of -80° C. The
evaporation of liquid ammonia by permitting it to escape into a pipe,
under reduced pressure, is used on a large scale as a means of producing
cold in cold storage and refrigeration plants. (See Fig. 157.)
[Illustration: FIG. 157.--Diagram of a refrigerating system.]
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