This process of depositing metals upon the surface of solids by an
electric current is called _electroplating_. Everyone has seen
_electroplated_ articles such as silver plated knives, forks, and
spoons, and nickel-plated rods, handles, etc. _Copper electrotype_
plates such as are used in printing school books are made by this
process. In practical electroplating a solution of the metal to be
deposited is placed in a tank; across the top of this tank are placed
copper rods to act as conducting supports. From one of these rods, the
cathode, objects to be plated are hung so as to be immersed in the
liquid. From other rods, the anodes, are hung plates of the metal to be
deposited. These are dissolved as the current deposits a coating upon
the articles, thus keeping the solution up to its proper strength. (See
Fig. 261.)
[Illustration: FIG. 262.--The current is carried through the solution by
ions.]
=281. Electrolysis.=--A solution from which a deposit is made by an
electric current is called an _electrolyte_. The plates or other objects
by which the current enters or leaves the electrolyte are called the
_electrodes_. The electrode by which the current enters is called the
_anode_ (_an_ = in) while the electrode by which it leaves is the
cathode (_cath_ = away). The process by which an electric current
decomposes a solution and deposits a substance upon an electrode is
called _electrolysis_. The _current_ always flows within the cell from
_anode to the cathode_. (See Fig. 262.) The metal goes with the current
and is found deposited upon the cathode.
=282. Theory of Electrolysis.=--The action going on in an _electrolytic_
cell has been carefully studied. The _theory of electrolysis_, which is
supported by much experimental evidence, supposes that many of the
molecules in a _dilute_ solution of a substance "split up" into two
parts called "ions," one ion having a positive, the other a negative
charge. In a dilute solution of sulphuric acid, the _positive_ ion is of
hydrogen, while the _negative_ ion is the (SO_{4}) or sulphion. These
ions bearing electric charges are believed to be the _carriers of the
electric current_ through the electrolyte.
The positive ions move with the current from the anode to the cathode,
while the negative ions apparently are repelled by the cathode and
appear upon the anode. Evidence of the accumulation of the two kinds of
ions at the two electrodes is furnished by the _electrolysis_ of water,
described below.
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