Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
For general utility no class of pigments can exceed the several
forms of Guignet’s green. It is capable of affording a great variety
of tints, all absolutely permanent under reasonable conditions. No
ordinary agent will decompose them, and they will stand almost any
test to which they may be subjected without losing colour. They are
quite insoluble in acids and alkalies, and are not affected even by the
extreme heat of the glass furnace. They possess good covering power,
do not suffer in brightness or purity under artificial light, and are
equally useful as oil or water colours, besides being admirably adapted
for fresco and silicious painting, and employed in making green glass
and in calico printing. They can be mixed with any other pigment.
Adulteration with Brunswick or Prussian greens is often practised, but
may be discovered by a portion being dissolved on boiling with caustic
soda, the solution giving a precipitate of chrome yellow on adding
acetic acid, and (a separate portion, of course) Prussian blue with
hydrochloric acid and perchloride of iron.
LOKAO.--This pigment, which is also known as “Chinese green,”
was first met with as a sediment left after dyeing cotton cloths
with the barks of one or more species of buckthorn, notably _Rhamnus
chlorophorus_ and _R. utilis_, and passing in China under the general
name of Lo-Kao. This sediment is spread on blotting paper and thus
dried, forming thin cakes. Latterly, the juice afforded by the berries
of the same trees is extracted by pressure, absorbed by alum, and dried
in the same form of little cakes. When first introduced into England
it was highly valued as affording a pure green, even in artificial
light. Its price on the London market in 1861 was 7_s._ 6_d._ an ounce.
So long ago as 1853 it was imported into France and used for dyeing
silk. The colouring principle appears to consist of a glucose (lokaose)
and an acid (lokaonic acid). In 1864, Chauvin obtained an identical
colouring matter from _Rhamnus catharticus_, or the common buckthorn,
a shrub which grows wild in most parts of Europe, and found a ready
market for the pigment at 37_s._ a pound. This was simply the article
known as sap green (see p. 132.)
MALACHITE.--This is one of the names applied to mountain green
(q.v.).
MANGANESE GREEN.--Several formulæ have been published for
making a green pigment from manganese, as follows:--
(1) An intimate mixture of 80 parts of nitrate of barium, 14 parts
of oxide of manganese and 6 parts of sulphate of barium, is placed
in a crucible and heated to bright redness until the green colour
is thoroughly developed. The fused green mass is poured out of the
crucible, cooled, and ground wet to a fine condition.
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