Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
_Characters._--Being virtually a hydrated silicate of alumina, china
clay is a remarkably stable pigment. Not only is it unaffected by
prolonged exposure to strong light and impure air, but is insoluble in
water, weak acids, and alkalies. It is moreover very much lighter in
weight than any other white pigment, an advantage on the score of cost
when buying by weight. Its covering power in distemper work and as a
water colour is good; but the addition of oil reduces its capacity.
The best qualities are exceedingly fine in grain and pure in tint, but
inferior samples sometimes have their yellowness “corrected” by the
addition of a little ultramarine.
ENAMELLED WHITE.--Another name for the finest kinds of baryta
white, see p. 170.
ENGLISH WHITE.--A synonym for whiting, see p. 246.
GYPSUM.--This very common and abundant mineral is a hydrated
sulphate of lime, occurring in several forms, of which only the opaque
white variety is useful as a pigment.
The native mineral is quarried, dressed, ground, and levigated, in all
which operations there is nothing special to be noted.
Whether obtained in this way, or prepared artificially, or formed as a
bye product in other industries, gypsum affords a permanent and neutral
white pigment, mixing well with oil or water, and possessing a covering
power which ranks between white lead and zinc white. It has a bluish
tint, but less so than ordinary white lead.
KAOLIN.--One of the names applied to china clay, see p. 172.
LEAD WHITES, OR WHITE LEADS.--On the grounds of the quantity
in which it is produced and the extent to which it is applied, probably
no pigment can compare with white lead, including in that term the
various white pigments having lead as a basis.
In its commonest form white lead is lead carbonate. There are many ways
in which it is made commercially, all dependent upon certain chemical
reactions.
When a solution of normal plumbic acetate is attacked by carbonic
acid, no precipitate is produced. That normal solution is formed by
the action of acetic acid or hydric acetate upon oxide of lead. It
consists of a certain weight of lead to a certain weight of acid, which
converts it into the acetate. Carbonic acid has no power to separate
out from it the lead, and form carbonate of lead. But this acetate of
lead has the power of dissolving a considerable quantity of oxide of
lead in addition to that which was used in its first formation, and
when this additional quantity of oxide of lead is dissolved by the
acetate, a substance is formed which is termed a basic acetate, that
means an acetate which contains more of the base (the lead oxide) than
the normal acetate itself does. From such a solution we are able to
precipitate, by means of carbonic acid, a white substance, which white
substance is a carbonate of lead.
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