Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
The results of numerous and repeated experiments on the larger scale
induced Condy to qualify the recommendation contained in his first
patent, viz. that of employing a solution of tribasic acetate of lead
and bicarbonate of soda in proper proportion to precipitate nearly the
whole of the lead, and further stating that he preferred to employ
“a slight excess of tribasic lead salt rather than find carbonate of
soda in excess.” Though, when carefully conducted, if the greatest
nicety is observed, a satisfactory result is obtained; in practice, the
least variation from the exact composition of the two substances is
attended with the drawback that the white lead is liable to a slight
uncertainty of tint after it is ground in oil, whereas by the process
hereinafter described a positive and reliable result can be obtained,
as the white lead produced will be of a uniform white colour, and not
liable to turn when ground in oil. Though the earlier process was in
itself complete for the manufacture of white lead from oxide of lead,
it afterwards occurred to Condy that a great object would be attained
in rendering the process more valuable and more practical, if a method
were devised, worked out, and described for the manufacture of tribasic
acetate of lead to be made entirely from metallic lead by the action of
acetic acid or neutral acetate of lead on metallic lead, and not to be
dependent on the employment in any way of previously manufactured oxide
of lead.
This portion of Condy’s invention relating to the manufacture of
tribasic acetate of lead may be described as follows: he melts, and,
after skimming carefully, feathers the metallic lead by dropping it
into water; he places this granulated lead in wooden vessels or vats
previously fitted with perforated false bottoms under which are fixed
taps for drawing the liquor off into other vats or tanks placed on a
lower level. Having filled with granulated lead the vessels fitted with
the false bottoms, he fills up the interstices with a dilute acetic
acid composed of one part, by weight, of acid (specific gravity 1·045
at 60° F.) and 12½ parts of water, and after allowing the dilute acid
to stand for two hours, draws it off through the taps into the lower
tanks. This allows access of atmospheric air to the lead, which has the
effect of heating the lead so that oxidation takes place.
Public-domain text, read in full here on John Shaqi.
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