Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
In working with this furnace, crushed ore (native sulphuret of lead)
and carbon, preferably in the state of pea or dust anthracite coal,
are mixed in equal proportions; the mixture is ignited, and the fumes
are oxidised by the blast through the mixture, which also promotes the
combustion. Dense white vapours or fumes pass off, and are conveyed to
a separate chamber, where they are strained by passing through a screen
or series of screens of muslin or other textile fabric. Lime may also
be employed in the furnace, in the proportion of 200 lb. of lime to 400
lb. of galena, although the addition of the lime is not necessary in
all cases.
Instead of the furnace above described, a muffle furnace may be
employed, in which the heat is applied indirectly to the ore, with
the precaution of constructing the sole or bottom of this furnace of
a material not rapidly acted on by the constituents of the ore; or
a reverberatory furnace may be used in which the heat is directly
applied. In both of these two cases reducing carbon may or may not be
mixed with the ore.
Sometimes, generated gas is employed in place of coal, to effect the
same result.
In a later specification Lewis remarks that when white lead pigment
is manufactured from galena or other lead ores, in the raw state, or
even in the roasted state, by subjecting them to the joint action of
heat and air, either with or without reducing means, according to the
quality of the lead ores used, the fumes are discoloured by particles
of carbon or sulphuret of lead, or both, when they are caught in bags
of textile fabric, and are unfit when in this state for use as a white
pigment.
The fumes which are produced by this action of heat and air on galena
or other lead ore are cooled and then collected in bags, and Lewis
prefers to expose the so-collected products to the joint action of
heat and air, to destroy or to burn out all the particles of carbon
or sulphuret of lead, or both, by either throwing the said fumes on
a bright clean anthracite or coke fire, with a blast from the sides
or from below, or by throwing them over such fires or into a cupola
furnace, or by throwing or blowing them into a generator gas flame, or
through externally heated retorts. He then in either case collects the
escaping fumes from the furnace or retort in bags or screening chambers.
The best process to be adopted depends upon the kind of fuel in the
locality where the fumes are refined, and also upon the purity of the
lead fumes. If they contain iron, clay, or the like, it is best to
throw them into a coal fire; but if they are pure, one process is about
as effective as the other, and the degree of purity of the fuel decides
the kind of heating apparatus to be used.
Public-domain text, read in full here on John Shaqi.
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