Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
_a_ is a vat, which may be made of wood or other material capable of
resisting the chemicals employed; it may conveniently be 6 feet in
diameter and 4 feet deep, and it is provided with a closely fitting
cover, _b_ is a cistern situate at a higher level, and intended to
contain a solution of acetate of ammonia, _c_ is a pipe by which the
solution can be drawn down from the cistern _b_ into the vat _a_; a
cock is provided upon this pipe, as the drawing indicates. There is a
man-hole _d_ in the cover of the vat, and the vat contains an agitator
_e_, with a vertical shaft which can be turned by gearing _f_ as shown,
or the agitator may be driven by any suitable motor. The shaft of the
agitator _e_ is hollow, and pipes _g_, which stand immediately behind
the stirring tines, are connected with the hollow shaft, to deliver
the carbonic acid gas into the vat; or this may be effected by means
of coils of pipe laid at the bottom of the vat, and pierced with small
holes. The pipes _g_ are open at their lower ends. _h_ is a cock by
which the liquor can be drawn off from the vat into the receiver _i_.
A pump _k_ is provided upon the cover of the receiver, by which the
liquor may be returned into the vat _a_. _l_ are outlets by which the
white lead is discharged from the
[Illustration: Fig. 26.--MACIVOR’S WHITE LEAD PLANT.]
vat into the washing cisterns _m_ and _n_. _o_ is a man-hole, which may
be opened to facilitate the emptying of the vat. _p_ is a plug which
is removed to let the white lead run out of the vat. _r_ is an ammonia
catch box, charged with acetic acid.
All the metal-work of the apparatus with which the acetate solution
comes into contact should be of such a character as to resist
corrosion, or should be coated with a material capable of withstanding
attack by the chemicals employed in or formed during the process.
The operation is by preference conducted in the following manner, but
the details admit of variation. The charge of monoxide of lead for an
apparatus of the dimensions indicated may weigh about 1120 lb.
The monoxide should be in fine powder, and may be either moist or dry.
Having received this charge, which is introduced by the upper man-hole
_d_, the vat _a_ is closed, and a solution of acetate of ammonia is
let down upon the charge from the cistern _b_, or pumped out of the
receiver _i_. The vat _a_ should be charged with the solution of
acetate of ammonia in the proportion of three parts of said solution
to one part of lead monoxide by weight. It is convenient to employ
a solution containing 5 per cent. of acetate of ammonia, and the
quantities above stated are suited to a solution of this strength; but
the strength of the acetate solution may be varied within wide limits,
as hereafter explained.
Public-domain text, read in full here on John Shaqi.
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