Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
Modern zinc yellows are invariably prepared from acid solutions, and
consist of a double salt of zinc chromate and potassium bichromate,
mixed with a varying amount of unchanged zinc oxide, which must not
be regarded as an adulteration of the pigment, for its presence gives
the substance “body.” As previously stated, sodium bichromate is
inadmissible, as it does not form similar double salts.
The raw material is usually zinc oxide, which is met with in a state
of great purity; by the addition of sulphuric acid, this is converted
into basic zinc sulphate; potassium bichromate solution is added, and
the whole is stirred vigorously for an hour. At the end of this time,
the zinc chromate, which was previously in a state of partial solution,
begins to separate out in the form of a brilliant yellow scum on the
surface of the liquid, consisting of (ZnCrO_{4})_{3}.K_{2}Cr_{2}O_{7},
while the solution rapidly becomes almost colourless. Suitable
proportions are:--Zinc oxide, 100 parts; sulphuric acid (66° B.) 60;
and potassium bichromate, 100. Although it is hardly possible that any
hydration takes place, it is found advisable to soak the zinc oxide in
water for 24 hours before the other reagents are added, the sulphuric
acid after dilution being added gradually. Great care must be taken
that the solutions are all cold, and the stirring is continuous, to
avoid the pigment being deposited in a hard sandy form. Zinc yellows
thus prepared are not liable to change during washing in a manner
analogous to the lead compounds.
Zinc chrome is not much used, partly because it is expensive, partly
because it cannot compete with the lead chromes in brilliance, depth of
colour, and body. Still, owing to the fact that it can be mixed with
sulphur pigments without change, it is often employed in the place of
the lead chromes. Pure zinc chrome is completely soluble in sulphuric
acid without any effervescence, but a slight effervescence may be
disregarded. Any residue may be put down as adulteration, and its
character can be ascertained by a few simple tests: it may be chrome
yellow, barytes, &c.
GAMBOGE.--Gamboge is a product of several trees of Eastern
Asia: viz. _Garcinia Morella_ var. β. _pedicellata_ [_G. Hanburyi_],
a native of Cambodia, the province of Chantibun in Siam, the islands
on the east coast of the Gulf of Siam, and the south parts of
Cochin China; _G. Morella_, growing in the moist forests of Ceylon
and Southern India; and _G. pictoria_, of Southern India, by some
considered identical with _G. Morella_. _G. travancorica_, of the
southern forests of Travancore and the Tinnevelly Ghâts, is capable
of affording small supplies of the pigment for local use, but not for
export.
Public-domain text, read in full here on John Shaqi.
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