Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
Alumina in a state suitable for the preparation of the pigments known
as “lakes” may be produced in the following manner:--Dissolve 1 lb. of
alum in ½ gallon of water, and add 75 grains of sulphate of copper,
and about ¼ lb. of zinc turnings; leave the mixture for three days in
a warm place, renewing the water lost by evaporation. The copper is
first deposited upon the zinc, the two metals thus forming a voltaic
couple sufficiently strong. Hydrogen is disengaged, sulphate of zinc
is formed, and the alumina gradually separates in the state of a
very fine powder; the action is allowed to continue until there is
no more alumina left in solution, or until ammonia ceases to give a
precipitate. If the reaction is prolonged beyond this point, oxide of
iron will precipitate if present. The alumina washes easily, and does
not contract upon drying.
BRAZIL-WOOD LAKE.--(_a_) Digest 1 lb. ground Brazil-wood in
4 gal. water for 24 hours, boil ½ hour, and add 1½ lb. alum dissolved
in a little water; mix, decant, strain, add ½ lb. tin solution, again
mix well, and filter; to the clear liquid cautiously add a solution of
carbonate of soda while a precipitate forms, avoiding excess; collect,
wash, and dry. The shade will vary according as the precipitate is
collected.
(_b_) Add washed and recently-precipitated alumina to a strong filtered
decoction of Brazil-wood.
CARMINATED LAKE.--(_a_) The cochineal residue left in making
carmine is boiled with repeated portions of water till exhausted;
the liquor is mixed with that decanted off the carmine, and at once
filtered; some recently-precipitated alumina is added, and the whole
is gently heated, and well agitated for a short time. As soon as the
alumina has absorbed enough colour, the mixture is allowed to settle,
the clear portion is decanted, and the lake is collected on a filter,
washed, and dried. The decanted liquor, if still coloured, is treated
with fresh alumina till exhausted, and thus a lake of second quality is
obtained.
(_b_) To the coloured liquor obtained from the carmine and cochineal
as just stated, a solution of alum is added, the filtered liquor is
precipitated with a solution of carbonate of potash, and the lake is
collected and treated as before. The colour is brightened by addition
of tin solution.
CARMINE.--Boil 1 lb. cochineal and 4 dr. carbonate of potash
in 7½ gal. water for ¼ hour. Remove from the fire, and stir in 8 dr.
powdered alum, and allow to settle for 20 to 30 minutes. Pour the
liquid into another vessel, and mix in a strained solution of 4 dr.
isinglass in 1 pint water; when a skin has formed upon the surface,
remove from the fire, stir rapidly, and allow to settle for ½ hour,
when the deposited carmine is carefully collected, drained, and dried.
Public-domain text, read in full here on John Shaqi.
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