Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
The luminosity of minerals has an obvious practical value in the case
of such substances as can be conveniently applied in the form of a
paint to surfaces which are alternately exposed to light and darkness,
such exposed surfaces emitting at one time the light which they have
absorbed at another. Familiar illustrations are street plates, buoys,
and interiors of railway carriages having to traverse many tunnels. The
light absorbed may be either daylight or powerful artificial light.
With this object, several compositions are prepared under the generic
name of luminous paints. They are chiefly as follows:--
(1) Balmain’s.--This consists of a phosphorescent substance introduced
into ordinary paint. The phosphorescent substance employed for the
purpose is a compound obtained by simply heating together a mixture of
lime and sulphur, or substances containing lime and sulphur, such as
alabaster, gypsum, &c., with carbon or other agent, to remove a portion
of the oxygen present; or by heating lime in a vapour containing
sulphur. In applying this phosphorescent powder, the best results are
obtained by mixing it with a colourless varnish made from mastic and
turpentine; drying oils, gums, pastes, sizes, &c., may, however, also
be used.
(2) A French compound.--100 lb. of a carbonate of lime and phosphate
of lime produced by the calcination of sea-shells, and especially
those of the genus _Tridacna_ and the cuttle-fish bone, intimately
mixed with 100 lb. of lime rendered chemically pure by calcination,
25 lb. of calcined sea-salt, 25-50 per cent. of the whole mass of
sulphur, incorporated by the process of sublimation, and 3-7 per cent.
of colouring matter in the form of powder composed of monosulphide of
calcium, barium, strontium, uranium, magnesium, aluminium, or other
mineral or substance producing the same physical appearances, _i.
e._ which, after having been impregnated with light becomes luminous
in the dark. After having mixed these five ingredients intimately,
the composition obtained is ready for use. In certain cases, and
more especially for augmenting the intensity and the duration of the
luminous effect of the composition, a sixth ingredient is added, in the
form of phosphorus reduced to powder, which is obtained from seaweed by
the well-known process of calcination. As to proportion, it is found
that the phosphorus contained in a quantity of seaweed, representing
25 per cent. of the weight of the composition formed by the five
above-named ingredients, gives very good results.
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