Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
The oxides usually added to the oil during boiling are litharge or
red-lead, the former being preferred on account of its lower price.
About 2-5 per cent. by weight of the oxides or dryers is gradually
stirred into the oil after it has been slowly raised to a temperature
of about 300° F. The stirring should be continued until the litharge is
dissolved, or it would cake on the bottom of the pan, and cause the oil
to burn. Litharge may even be reduced to a cake of metallic lead when
the fire is brisk. Some pans are furnished with stirrers and gearing by
which the latter can be worked, either by hand or steam. The material
of which the pans are made is either wrought or cast iron. Copper pans
are sometimes used with the object of improving the colour of the oil.
Little is known respecting the chemical reactions which take place
during the boiling of oil. Even when the air is excluded during the
process, the drying properties are greatly increased, and, if boiled
long enough, the oil is converted into a solid substance. The loss of
weight which ensues is dependent upon the temperature and the time
during which the operation continues. It is less when the air is freely
admitted than if the pan is covered with a hood. The vapours given off
by the oil are of an extremely irritating character, and should be
destroyed by passing them through a furnace. As their mixture with air
in certain proportions is explosive, this furnace should be situated
at some distance, and the gases be conducted into it by means of an
earthenware pipe.
Since zinc oxide has been introduced as a substitute for white lead in
painting, researches have been made to replace litharge as a dryer,
because it is not logical to discard the lead pigment and then use a
lead dryer with a zinc pigment.
Several metallic oxides and salts, especially zinc sulphate, manganese
oxide, and umber, have the property of combining with oils, which they
render drying. To these may be added the protoxides of the metals of
the third class, i. e. iron, cobalt, and tin. But these oxides are very
unstable and difficult of preparation; hence it became desirable to
discover some means by which they might be combined with bodies which
would enable them to be prepared cheaply, and at the same time leave
unimpaired their desiccating powers. Moreover, it is acknowledged that
dryers in the dry state are preferable in many respects to drying oils.
Following are some of the recently introduced dryers:--
Public-domain text, read in full here on John Shaqi.
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