Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
_Drying._--The drying of paint is to a great extent dependent upon the
temperature. Below the freezing point of water, paint will remain wet
for weeks, even when mixed with a considerable proportion of dryers;
while, if exposed to a heat of 120° F. the same paint will become solid
in a few hours. The drying of paint being a process of oxidation, and
not evaporation, it is essential that a good supply of fresh air should
be provided. When a film of fresh paint is placed with air in a closed
vessel, it does not absorb the whole of the oxygen present; but after a
time the drying process is arrested, and the remaining oxygen appears
to have become inert.
Considerable quantities of volatile vapours are given off during the
drying of paint; these are due to the decomposition of the oil. When
the paint has been thinned down by turpentine, the whole of this
liquid evaporates on exposure to the air. There must, therefore, be
a plentiful access of air, to remove the vapours formed, and afford
a fresh supply of active oxygen. The presence of moisture in the air
is rather beneficial than injurious at this stage. Especially in the
case of paints mixed with varnish, moist air appears to counteract the
tendency to crack or shrink. Under the erroneous impression that the
drying of paint is a species of evaporation, open fires are sometimes
kept up in freshly-painted rooms. It is only when the temperature is
very low that any benefit can result from this practice; as a rule, it
rather retards than hastens the solidification of the oil, which cannot
take place rapidly in an atmosphere laden with carbonic acid.
The first coat of paint should be thoroughly dry before the second is
applied. Acrylic acid is formed during the oxidation of linseed-oil,
and unless this be allowed to evaporate, it may subsequently liberate
carbonic acid from the white lead present in most paints, and give rise
to blisters. Sometimes a second priming-coat is given; but usually
the second coat applied contains the pigment. This, as soon as dry,
is again covered by another coat, and subsequently by two or more
finishing coats, according to the nature of the work.
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