Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
It is curious that chemically pure sodium carbonate, or such as is made
by the ammonia-soda process, is not well fitted for the manufacture of
ultramarine; Leblanc soda, containing a little caustic, is distinctly
preferable. Sprinkling the soda with a strong solution of sodium
sulphide before use is a good plan, and one easy to adopt. The more
silicious the mixture the more difficulties are encountered, but the
product is a deeper, richer colour, and withstands the action of alum
and weak acids better. Excess of oxygen must be guarded against; many
a manufacturer has had a batch turn out a hard cold blue, instead of
a soft rich colour, solely on account of a too-excellent draught,
an accident especially liable to happen in winter time. So much
dreaded is this catastrophe that some makers habitually limit the air
supply--smothering the neighbourhood with smoke, and wasting coal. The
need for exact control here indicated points to a probable advantage
from the use of gaseous fuel. Considerable economy has resulted from
the use of the waste gases from one furnace serving for the preliminary
heating of another; a better plan would probably be the introduction of
regenerative heating.
The crude ultramarine as it comes from the furnace contains a large
proportion of soluble salts, notably 20 to 24 per cent. of sodium
sulphate, which have to be removed before it is merchantable. Usually,
after grinding, it is simply stirred up repeatedly with hot water and
the aqueous extract is siphoned off. That such a crude method should be
in vogue at the present time is very significant of the ample margin
of profit that must exist. By systematic extraction and filtration
under pressure the washing may be effected with so little water that
the solution is sufficiently concentrated to pay for evaporation by the
heat of waste furnace gases, the recovered sodium sulphate serving to
replace part of the raw material.
The quality of ultramarine largely depending upon its fineness, it
is graded by levigation, the coarser portions being filter pressed,
and the finest “floating” quality, which remains in suspension for an
inconveniently long time, precipitated by the addition of a trace of an
ammonium salt, gypsum, or even hard water, and filtered by the aid of a
suction tube on the principle of an ordinary Bunsen pump.
Public-domain text, read in full here on John Shaqi.
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