Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
“The mixture undergoes a very curious change of colour while in the
ovens. When put in it is greyish white, and during the process of
burning it becomes successively brown, green, blue, violet, red and
white, in the order named. These changes are, according to Guimet,
due to oxidation. The brown appears with the blue flames due to the
combustion of the sulphur, the green just after the sulphur flames have
ceased, and the blue is first formed at a temperature of about 700°--i.
e. a bright red heat. If, after this, heat be still applied and air
freely admitted, the mixture becomes first violet, then red or rose
coloured, and finally white. When this white body is heated to redness
with carbon or other reducing agents, the red, violet, blue, green and
brown colours (according to the amount of reducing agent employed) may
sometimes be reproduced, though the reaction is by no means a certain
one.
“If brown ultramarine be removed from the oven, and allowed to remain
exposed to the air, it immediately takes fire and burns to an inferior
blue colour. The same thing occurs with the green body. Even if the
brown product be completely cooled before being exposed to the air,
it will, as soon as the air is allowed to reach it, get hotter and
hotter, until it is glowing, when it will burst into flame and become
blue. Attempts have been made to preserve the brown colour, which is of
a beautiful chocolate tint, but have always failed. In one instance,
when this was tried, the colour was put immediately into water, and
treated like the ordinary blue variety, and as long as it was kept
moist no change was apparent. After being washed and wet ground the
moist powder was put into a cask, where for some time it was allowed to
remain undisturbed. At the end of about three weeks it was noticed that
the mass was hot, and on being turned out of the cask and broken up it
was found to be at a glowing heat in the interior.
“After the oven has been fired for several hours, it is carefully
closed at every point where air might enter, and allowed to cool
for four or five days. The exact length of time during which the
ovens are fired, and the amount of air admitted, depend upon various
circumstances, one important one being the state of the weather. Thus,
on a dull, foggy day, when the draught in the chimney is not good, a
longer time is required. Of course, no rule can be given for this,
and it is the experience required in the management of the oven that
makes the manufacture so difficult to carry out successfully, the early
efforts of a manufacturer not unfrequently resulting in the loss of
a whole ovenful of raw material. As soon as the oven has cooled, the
crucibles are taken out, and the contents of each are turned out in a
solid mass, which must be carefully cleaned with a knife of any badly
burned portions, and afterwards broken up and thrown into a cask along
with the contents of other crucibles.
Public-domain text, read in full here on John Shaqi.
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