Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
(2) Place 2 parts by weight of copper-filings in a vessel capable
of being tightly closed, and over them pour 3 parts by weight of
salammoniac in the form of a saturated aqueous solution. Keep the
mixture in a warm place for some weeks and thoroughly agitate it
occasionally. In due time the newly formed oxychloride is removed from
the vessel, and separated from the non-oxidised copper by washing on a
sieve. This washing must be continued until all traces of alkali have
been destroyed, when the pigment is drained, and very slowly dried at a
low temperature to avoid decomposition.
(3) Copper scrap is covered with a concentrated solution of chloride
of copper and allowed to remain until the chloride has undergone
conversion into basic chloride. The latter is then subjected to the
straining, washing, and drying treatment prescribed in (2).
(4) In a lead-lined vessel, place a quantity of copper filings or
waste, and add to it two-thirds of its weight of common salt, and
one-third of its weight of concentrated sulphuric acid, the latter
being however first diluted by admixture with three times its volume
of water. The mass is left to stand, with occasional stirring till all
the copper has been transformed into oxychloride, when it is strained,
washed, and dried as in (2).
(5) A modification of (4) is to put the copper scrap into a wooden
vessel, and cover it with an equal weight of common salt and an equal
weight of sulphate of potash dissolved in water. After standing and
agitation as before, the oxychloride is formed, and the straining,
washing, and drying are repeated.
(6) A solution of crude carbonate of ammonia is added to a mixed
solution of alum and blue vitriol so long as any reaction takes place.
When it is completed, the precipitate is collected, washed, and dried
as in the other cases.
(7) Lighter shades are produced by the addition of alum, or of sulphate
of baryta.
(_b_) New process.
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