Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
In the wet method there is this essential difference, that it is
sought to precipitate the blue and yellow colours upon the inert base
by bringing about certain reactions, and therefore while the base
remains the same as in the dry method, the colouring media are totally
distinct, consisting of lead acetate, bichromate of potash, sulphate
of iron, and yellow or red prussiate of potash. The chief condition
to be observed with regard to the lead acetate is that it shall be in
the proportion of slightly more than three to one of the bichromate
of potash; in other words, the bichromate should be a trifle less
than one-third the weight of the lead acetate. As to the iron salt,
if commercial acetate or nitrate of iron could be bought of constant
quality or purity, that would be the most convenient form; but failing
that, recourse is had to freshly made and good quality sulphate of iron
(green copperas). It is found that the best results are secured when
the weight of the sulphate of iron is exactly the same as that of the
prussiate of potash. On the score of economy, the yellow prussiate of
potash (ferrocyanide) is employed, but the red prussiate (ferricyanide
of potassium) gives better and more certain results, and should be
adopted when making a superior paint which will command a higher price.
As to the comparative merits of the wet and dry systems of mixing the
ingredients of Brunswick greens, preference must be given to the former
on the score of quality of the pigment produced, but on the other hand
it entails much more trouble and skill, and there never can be the
same degree of control over the conduct of the operation or the shade
of colour developed. The dry method, however, though much more easily
carried out, and enabling the exact shade desired to be obtained to a
nicety by adding a little more of either the blue or the yellow during
the process of manufacture, is seldom adopted, because the quality and
fineness of the tints thus secured are much inferior.
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