Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
The Brunswick greens are in the front rank of green pigments so far as
covering power is concerned, and, when made from reliable materials,
are reasonably durable under the influence of air and light, in which
respect, however, they vary considerably. They can be used as water
colours, but are superior in oil paints. Precautions are necessary
in mixing them with other pigments. By the action of sulphuretted
hydrogen, or sulphur in any form, the colour is darkened to a notable
degree; by the action of acids, the chrome is destroyed and the green
becomes blue; by the action of alkalies, both the blue and the yellow
constituents are affected, and the green gives place to a reddish hue.
The pale and medium shades are yellow greens; the deep and extra deep
are blue greens.
These colours can be distinguished by heating them with caustic soda,
which turns them brownish in tone, owing to the destruction of the
Prussian blue. If the residue be filtered, and to the filtrate some
acid and ferric chloride be added, a blue precipitate will be obtained,
indicative of the presence of Prussian blue. On washing the residue
with water and treating with hydrochloric acid, the brown colour
disappears, and, in most cases, only a white residue of barytes is
left; sometimes the residue may have a faint yellowish colour. The
solution in hydrochloric acid will give the characteristic tests for
iron. The yellow element can be recognised by boiling in hydrochloric
acid, filtering, and allowing the filtrate to cool, when crystals of
lead chloride will deposit; these, separated out and dissolved in
boiling water, will give the characteristic tests for lead, such as
a white precipitate with sulphuric acid, and yellow precipitate with
bichromate of potash. The filtrate will have a green colour, indicative
of chromium.
CHINESE GREEN.--Another name for the vegetable pigment known
in China as Lokao (q.v.)
CHROME GREEN.--This name is often applied to any green in
which chrome enters as an element, but more particularly to the modern
Brunswick greens described on pp. 114-118; and to the green which bears
the name of its first maker, Guignet, and described under the title of
Guignet’s Green, see p. 125.
COBALT GREEN.--This remarkably stable, but somewhat costly,
pigment is also known by the names of Rinmann green and zinc green,
the former after the name of the chemist who first prepared it, and
the latter because it contains a large proportion of zinc. It is in
fact a combination of the oxides of cobalt and zinc, and was originally
produced in the following manner:-½ lb. pure cobalt ore was dissolved
in 4 lb. concentrated nitric acid, and added to a solution of 1 lb.
zinc in 5 lb. nitric acid; the mixture was diluted with water, and
a solution of potash carbonate was added, throwing down a pinkish
precipitate, which was washed on a filter, dried, and calcined at a
high temperature.
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