Poisons, Their Effects and Detection: A Manual for the Use of Analytical Chemists and ExpertsBlyth, Alexander Wynter
Science
Poisons, Their Effects and Detection: A Manual for the Use of Analytical Chemists and Experts
Blyth, Alexander Wynter
Poisons
When there is sufficient of the blood present to obtain a few milligrms.
of ash, there is a means of distinguishing human blood from that of
other common mammals, which has been neglected by authorities on the
subject, and which may be found of real value. Its principle depends
upon the relative amounts of potassium and sodium in the blood of man as
compared with that in the blood of domestic animals. In the blood of the
cow, sheep, fowl, pig, and horse, the sodium very much exceeds the
potassium in the ash; thus the proportion of sodium oxide to that of
potassium oxide in the blood of the sheep is as K₂O ·1 : Na₂O ·6; in
that of the cow, as 1 : 8; in that of the domestic fowl, as 1 : 16;
while the same substances in human blood are sometimes equal, and vary
from 1 : 1 to 1 : 4 as extremes, the mean numbers being as 1 : 2·2. The
potassium is greater in quantity in the blood-corpuscles than in the
blood serum; but, even in blood serum, the same marked differences
between the blood of man and that of many animals is apparent. Thus, the
proportion of potash to soda being as 1 : 10 in human blood, the
proportion in sheep’s blood is 1 to 15·7; in horse’s serum as 1 to 16·4;
and in the ox as 1 to 17. Since blood, when burnt, leaves from 6 to 7
per thousand of ash, it follows that a quantitative analysis of the
relative amounts of potassium and sodium can only be satisfactorily
effected when sufficient of the blood is at the analyst’s disposal to
give a weighable quantity of mineral matter. On the other hand, much
work requires to be done before this method of determining that the
blood is either human, or, at all events, not that of an herbivorous
animal, can be relied on. We know but little as to the effect of the
ingestion of sodium or potassium salts on either man or animals, and it
is possible--nay, probable--that a more or less entire substitution of
the one for the other may, on certain diets, take place. Bunge seems in
some experiments to have found no sodium in the blood of either the cat
or the dog.
The source from which the blood has emanated may, in a few cases, be
conjectured from the discovery, by microscopical examination, of hair or
of buccal, nasal, or vaginal epithelium, &c., mixed with the
blood-stain.
PART III.--POISONOUS GASES: CARBON MONOXIDE--CHLORINE--HYDRIC SULPHIDE.
I.--Carbon Monoxide.
§ 37. Carbon monoxide, CO, is a colourless, odourless gas of 0·96709 sp.
gravity. A litre weighs 1·25133 grm. It is practically insoluble in
water. It unites with many metals, forming gaseous or volatile
compounds, _e.g._, nickel carbon oxide, Ni(CO)₄, is a fluid volatilising
at 40°. These compounds have, so far as is known, the same effects as
CO.
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