Poisons, Their Effects and Detection: A Manual for the Use of Analytical Chemists and ExpertsBlyth, Alexander Wynter
Science
Poisons, Their Effects and Detection: A Manual for the Use of Analytical Chemists and Experts
Blyth, Alexander Wynter
Poisons
The general characters of sulphuric acid are as follows:--When pure, it
is a colourless, or, when impure, a dark brown to black, oily liquid,
without odour at common temperatures, of an exceedingly acid taste,
charring most organic tissues rapidly, and, if mixed with water,
evolving much heat. If 4 parts of the strong acid are mixed with 1 part
of water at 0°, the mixture rises to a heat of 100°; a still greater
heat is evolved by mixing 75 parts of acid with 27 of water.
Sulphuric acid is powerfully hygroscopic--3 parts will, in an ordinary
atmosphere, increase to nearly 4 in twenty-four hours; in common with
all acids, it reddens litmus, yellows cochineal, and changes all
vegetable colours. There is another form of sulphuric acid, extensively
used in the arts, known under the name of “Nordhausen sulphuric acid,”
“fuming acid,” formula H₂S₂O₄. This acid is produced by the distillation
of dry ferrous sulphate, at a nearly white heat--either in earthenware
or in green glass retorts; the distillate is received in sulphuric acid.
As thus manufactured, it is a dark fuming liquid of 1·9 specific
gravity, and boiling at 53°. When artificially cooled down to 0°, the
acid gradually deposits crystals, which consist of a definite compound
of 2 atoms of anhydrous sulphuric acid and 1 atom of water. There is
some doubt as to the molecular composition of Nordhausen acid; it is
usually considered as hydric sulphate saturated with sulphur dioxide.
This acid is manufactured chiefly in Bohemia, and is used, on a large
scale, as a solvent for alizarine.
§ 52. =Sulphur Trioxide, or Sulphuric Anhydride= (SO₃), itself may be
met with in scientific laboratories, but is not in commerce. Sulphur
trioxide forms thin needle-shaped crystals, arranged in feathery groups.
Seen in mass, it is white, and has something the appearance of asbestos.
It fuses to a liquid at about 18°, boils at 35°, but, after this
operation has been performed, the substance assumes an allotropic
condition, and then remains solid up to 100°; above 100° it melts,
volatilises, and returns to its normal condition. Sulphuric anhydride
hisses when it is thrown into water, chemical combination taking place
and sulphuric acid being formed. Sulphur trioxide is excessively
corrosive and poisonous.
Besides the above forms of acid, there is an officinal preparation
called “Aromatic Sulphuric Acid,” made by digesting sulphuric acid,
rectified spirit, ginger, and cinnamon together. It contains 10·19 per
cent. of SO₃, alcohol, and principles extracted from cinnamon and
ginger.
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