Poisons, Their Effects and Detection: A Manual for the Use of Analytical Chemists and ExpertsBlyth, Alexander Wynter
Science
Poisons, Their Effects and Detection: A Manual for the Use of Analytical Chemists and Experts
Blyth, Alexander Wynter
Poisons
The uses of the liquid acid are mainly in the production of chlorine, as
a solvent for metals, and for medicinal and chemical purposes. Its
properties are briefly as follows:--
It is a colourless or faintly-yellow acid liquid, the depth of colour
depending on its purity, and especially its freedom from iron. The
liquid is volatile, and can be separated from fixed matters and the less
volatile acids by distillation; it has a strong attraction for water,
and fumes when exposed to the air, from becoming saturated with aqueous
vapour. If exposed to the vapour of ammonia, extremely dense clouds
arise, due to the formation of the solid ammonium chloride. The acid,
boiled with a small quantity of manganese binoxide, evolves chlorine.
Dioxide of lead has a similar action; the chlorine may be detected by
its bleaching action on a piece of paper dipped in indigo blue; a little
zinc foil immersed in the acid disengages hydrogen. These two
tests--viz., the production of chlorine by the one, and the production
of hydrogen by the other--separate and reveal the constituent parts of
the acid. Hydrochloric acid, in common with chlorides, gives a dense
precipitate with silver nitrate. The precipitate is insoluble in nitric
acid, but soluble in ammonia; it melts without decomposition. Exposed to
the light, it becomes of a purple or blackish colour. Every 100 parts of
silver chloride are equal to 25·43 of hydrochloric acid, HCl, and to
63·5 parts of the liquid acid of specific gravity 1·20.
The properties of pure hydrochloric acid gas are as follows:--Specific
gravity 1·262, consisting of equal volumes of hydrogen and chlorine,
united without condensation. 100 cubic inches must therefore have a
weight of 39·36 grains. The gas was liquefied by Faraday by means of a
pressure of 40 atmospheres at 10°; it was colourless, and had a less
refractive index than water.
Water absorbs the gas with avidity, 100 volumes of water absorbing
48,000 volumes of the gas, and becoming 142 volumes. The solution has
all the properties of strong hydrochloric acid, specific gravity 1·21.
The dilute hydrochloric acid of the Pharmacopœia should have a specific
gravity of 1·052, and be equivalent to 10·58 per cent. of HCl.
§69. =Statistics of Poisoning by Hydrochloric Acid.=--The following
tables give the deaths, with age and sex distribution, due to
hydrochloric acid for ten years (1883-92):--
DEATHS FROM HYDROCHLORIC ACID IN ENGLAND AND WALES DURING THE TEN YEARS
ENDING 1892.
ACCIDENT OR NEGLIGENCE.
Ages, Under 1-5 5-15 15-25 25-65 65 and Total
1 above
Males, 1 16 2 ... 26 3 48
Females, ... 8 ... ... 9 1 18
----------------------------------------------------
Totals, 1 24 2 ... 35 4 66
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