Poisons, Their Effects and Detection: A Manual for the Use of Analytical Chemists and ExpertsBlyth, Alexander Wynter
Science
Poisons, Their Effects and Detection: A Manual for the Use of Analytical Chemists and Experts
Blyth, Alexander Wynter
Poisons
[92] Those who desire to study more closely the effect of acids
generally on vegetation may consult the various papers of the alkali
inspectors contained in the Local Government Reports. See also
Schubarth, _Die saueren Gase, welche Schwefelsäure- und Soda-Fabriken
verbreiten_. _Verhandlungen des Vereins zur Beförderung des
Gewerbefleisses in Preussen_, 1857, S. 135. Dingler’s _Journal_, Bd.
145, S. 374-427.
Christel, _Ueber die Einwirkung von Säuren-Dämpfen auf die Vegetation_.
_Arch. f. Pharmacie_, 1871, p. 252.
_Vierteljahrsschrift für gerichtliche Medicin_, 17 Bd. S. 404, 1872.
§73. =Action upon Cloth and Manufactured Articles.=--On black cloth the
acid produces a green stain, which is not moist and shows no corrosion.
On most matters the stain is more or less reddish; after a little time
no free acid may be detected, by simply moistening the spot; but if the
stain is cut out and boiled with water, there may be some evidence of
free acid. The absence of moisture and corrosion distinguishes the stain
from that produced by sulphuric acid.
§74. =Poisonous Effects of Hydrochloric Acid Gas.=--Eulenberg[93] has
studied the effects of the vapour of this acid on rabbits and pigeons.
One of these experiments may be cited in detail. Hydrochloric acid gas,
prepared by heating together common salt and sulphuric acid, was passed
into a glass shade supported on a plate, and a rabbit was placed in the
transparent chamber thus formed. On the entrance of the vapour, there
was immediate blinking of the eyes, rubbing of the paws against the
nostrils, and emission of white fumes with the expired breath, while the
respiration was irregular (40 to the minute). After the lapse of ten
minutes, the gas was again introduced, until the atmosphere was quite
thick; the symptoms were similar to those detailed above, but more
violent; and in fourteen minutes from the commencement, the rabbit sank
down on its right side (respirations 32). When twenty-two minutes had
elapsed, the gas was again allowed to enter. The rabbit now lay quiet,
with closed eyes and laboured respiration, and, finally, after
half-an-hour of intermittent exposure to the gas, the animal was
removed.
[93] _Gewerbe Hygiene_, Berlin, 1876, S. 51.
The cornea were opalescent, and the eyes filled with water; there was
frequent shaking of the head and working of the forepaws. After three
minutes’ exposure to the air, the respirations were found to be 128 per
minute; this quickened respiration lasted for an hour, then gave place
to a shorter and more superficial breathing. On the second day after the
experiment, the rabbit suffered from laboured respiration (28 to the
minute) and pain, and there was a rattling in the bronchial tubes. The
animal died on the third day, death being preceded by slow respiration
(12 to the minute).
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