Poisons, Their Effects and Detection: A Manual for the Use of Analytical Chemists and ExpertsBlyth, Alexander Wynter
Science
Poisons, Their Effects and Detection: A Manual for the Use of Analytical Chemists and Experts
Blyth, Alexander Wynter
Poisons
In Germany the officinal acid is of 1·185 specific gravity,
corresponding to about 30 per cent. of HNO₃. The dilute nitric acid of
the Pharmacopœia is a colourless liquid, of specific gravity 1·101, and
should contain about 17·4 per cent. of acid. The acids used in various
industries are known respectively as _dyers’_ and _engravers’_ acid.
_Dyers’_ acid has a specific gravity of 1·33 to 1·34 (66° to 68° Twad.),
that is, strength from 56 to 58 per cent. of HNO₃. _Engravers’_ acid is
stronger; being of 1·40 specific gravity (80° Twad.); and contains 70
per cent. of HNO₃. Although the _pure_ acid of commerce is (and should
be) almost colourless, most commercial specimens are of hues from yellow
up to deep red. An acid saturated with red oxides of nitrogen is often
known as “fuming nitric acid.”
§ 80. =Use in the Arts.=--Nitric acid is employed very extensively in
the arts and manufactures. The dyer uses it as a solvent for tin in the
preparation of valuable mordants for calico and other fabrics; the
engraver uses it for etching copper. It is an indispensable agent in the
manufacture of gun-cotton, nitro-glycerin, picric acid, and sulphuric
acid; it is also used in the manufacture of tallow, in preparing the
felt for hats, and in the gilding trades. It is said to be utilised to
make yellowish or fawn-coloured spots on cigar leaves, so as to give
them the appearance of age and quality. It is also used as a medicine.
§ 81. =Statistics of Poisoning by Nitric Acid.=--In the ten years
1883-1892 no case of murder was ascribed to nitric acid, but it caused
accidentally 25 deaths, and was used in 27 cases of suicide.
The following tables give the age and sex distribution of these
deaths:--
DEATHS IN ENGLAND AND WALES DURING THE TEN YEARS ENDING 1892 FROM NITRIC
ACID.
ACCIDENT OR NEGLIGENCE.
Ages, 1-5 5-15 15-25 25-65 65 and Total
above
Males, 6 2 1 9 ... 18
Females, 3 ... ... 4 ... 7
--------------------------------------
Totals, 9 2 1 13 ... 25
--------------------------------------
SUICIDE.
Ages, 15-25 25-65 65 and Total
above
Males, 3 14 1 18
Females, 1 8 ... 9
----------------------------
Totals, 4 22 1 27
----------------------------
§ 82. =Fatal Dose.=--The dose which causes death has not been
ascertained with any exactness. As in the case of sulphuric acid, we may
go so far as to say that it is possible for a few drops of the strong
acid to be fatal, for if brought into contact with the vocal apparatus,
fatal spasm of the glottis might be excited. The smallest dose on record
is 7·7 grms. (2 drachms), which killed a child aged 13.
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