Poisons, Their Effects and Detection: A Manual for the Use of Analytical Chemists and ExpertsBlyth, Alexander Wynter
Science
Poisons, Their Effects and Detection: A Manual for the Use of Analytical Chemists and Experts
Blyth, Alexander Wynter
Poisons
§ 86. =Local Action.=--When strong nitric acid comes in contact with
organic matters, there is almost constantly a development of gas. The
tissue is first bleached, and then becomes of a more or less intense
yellow colour. Nitric acid spots on the skin are not removed by ammonia,
but become of an orange-red when moistened with potash and a solution of
cyanide of potassium. The yellow colour seems to show that picric acid
is one of the constant products of the reaction; sulphide of ammonium
forms a sort of soap with the epidermis thus attacked, and detaches it.
§ 87. =Symptoms.=--The symptoms and course of nitric acid poisoning
differ in a few details only from those of sulphuric acid. There is the
same instant pain and frequent vomiting, destruction of the mucous
membranes, and, in the less severe cases, after-contraction of the
gullet, &c.
One of the differences in the action of nitric and sulphuric acids is
the constant development of gas with the former. This, without doubt,
adds to the suffering. Tartra made several experiments on dead bodies,
and showed that very considerable distension of the intestinal canal, by
gaseous products, was the constant result; the tissues were corroded and
almost dissolved, being transformed, ultimately, into a sort of greasy
paste. The vomited matters are of a yellow colour, unless mixed with
blood, when they are of a dirty-brown hue, with shreds of yellow mucus,
and have the strong acid reaction and smell of nitric acid. The teeth
may be partially attacked from the solvent action of the acid on the
enamel. The fauces and tongue, at first blanched, soon acquire a
citron-yellow, or even a brown colour; the whole cavity may swell and
inflame, rendering the swallowing of liquids difficult, painful, and
sometimes impossible. The air passages may also become affected, and in
one case tracheotomy was performed for the relief of the breathing.[111]
The stomach rejects all remedies; there are symptoms of collapse; quick,
weak pulse, frequent shivering, obstinate constipation, and death (often
preceded by a kind of stupor) in from eighteen to twenty-four hours. The
intellectual faculties remain clear, save in a few rare instances.
[111] Arnott, _Med. Gaz._, vol. xii. p. 220.
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