Poisons, Their Effects and Detection: A Manual for the Use of Analytical Chemists and ExpertsBlyth, Alexander Wynter
Science
Poisons, Their Effects and Detection: A Manual for the Use of Analytical Chemists and Experts
Blyth, Alexander Wynter
Poisons
In most cases, it will be well to proceed as follows:--The contents
of the stomach are, if necessary, diluted with distilled water, and
divided into three parts, one of which is submitted to dialysis, and
then the dialysed liquid evaporated to a small bulk and examined
qualitatively, in order to ascertain whether a large amount of the
alkaline salts is present, and in what form. In this way, the
presence or absence of nitrate of potassium or sodium may be proved,
or the iodide, bromide, sulphate, and chlorate detected.
To find, in this way, nitrate of potassium, a coarse test is
preferable to the finer tests dependent upon conversion of the
nitrate into nitrites or into ammonia, for these tests are so
delicate, that nitrates may be detected in traces; whereas, in this
examination, to find traces is of no value. Hence, the old-fashioned
test of treating the concentrated liquid in a test-tube with copper
filings and then with sulphuric acid, and looking for the red fumes,
is best, and will act very well, even should, as is commonly the
case, some organic matters have passed through the dialyser.
Chlorates are indicated if the liquid is divided into two parts and
tested in the manner recommended at p. 127. If present in any
quantity, chlorates or nitrates may be indicated by the brilliant
combustion of the organic matter when heated to redness, as also by
the action of strong sulphuric acid on the solid substances--in the
one case, yellow vapours of peroxide of chlorine being evolved--in
the other, the red fumes already mentioned of nitric peroxide.
With regard to a substance such as the hydro-potassic tartrate, its
insolubility in water renders it not easy of detection by dialysis;
but its very insolubility will aid the analyst, for the contents of
the stomach may be treated with water, and thus all soluble salts of
the alkalies extracted. On now microscopically examining the
insoluble residue, crystals of bitartrate, if present, will be
readily seen. They may be picked up on a clean platinum wire and
heated to redness in a Bunsen flame, and spectroscopically examined.
After heating, the melted mass will have an alkaline reaction, and
give a precipitate with platinic chloride. All other organic salts
of potassium are soluble, and a white crystal giving such reaction
must be hydro-potassic tartrate.
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