Poisons, Their Effects and Detection: A Manual for the Use of Analytical Chemists and ExpertsBlyth, Alexander Wynter
Science
Poisons, Their Effects and Detection: A Manual for the Use of Analytical Chemists and Experts
Blyth, Alexander Wynter
Poisons
§ 142. =Paraffin Oil= (or =kerosine, mineral oil, photogen=, &c.) is
the chief product resulting from the distillation of American
petroleum--the usual specific gravity is about ·802--it is a mixture
of hydrocarbons of the paraffin series. It should be free from the
more volatile constituents, and hence should not take fire when a
flame is applied near the surface of the cold liquid.
§ 143. =Effects of Petroleum.=--Since we have here to deal with a
commercial substance of such different degrees of purity, and
various samples of which are composed of such various proportions of
different hydrocarbons, its action can only be stated in very
general terms. Eulenberg[133] has experimented with the lighter
products obtained from the distillation of Canadian petroleum. This
contained sulphur products, and was extremely poisonous, the vapour
killing a rabbit in a short time, with previous insensibility and
convulsions. The autopsy showed a thin extravasation of blood on the
surface of each of the bulbi, much coagulated blood in the heart,
congested lungs, and a bloody mucus covering the tracheal mucous
membrane. An experiment made on a cat with the lighter petroleum
(which had no excess of sulphur) in the state of vapour, showed that
it was an anæsthetic, the anæsthesia being accompanied by
convulsions, which towards the end were tetanic and violent. The
evaporation of 1·5 grm. in a close chamber killed the animal in
three hours. The lungs were found congested, but little else was
remarkable. Much petroleum vapour is breathed in certain factories,
especially those in which petroleum is refined.[134] From this cause
there have been rather frequent toxic symptoms among the workmen.
Eulenberg[135] describes the symptoms as follows:--A person, after
breathing an overdose of the vapour, becomes very pale, the lips are
livid, the respiration slow, the heart’s action weak and scarcely to
be felt. If he does not immediately go into the open air away from
the poisonous vapour, these symptoms may pass on to insensibility,
convulsions, and death. It often occasions a condition of the
voluntary muscles similar to that induced by drunkenness, and on
recovery the patient is troubled by singing in the ears and noises
in the head. The smell and taste of the poison may remain for a long
time.
[133] _Gewerbe-Hygiene._
[134] The vapour most likely to rise at the ordinary temperature, and
mix with the atmosphere, is that of the lighter series, from cymogene to
benzoline.
[135] _Op. cit._
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