Poisons, Their Effects and Detection: A Manual for the Use of Analytical Chemists and ExpertsBlyth, Alexander Wynter
Science
Poisons, Their Effects and Detection: A Manual for the Use of Analytical Chemists and Experts
Blyth, Alexander Wynter
Poisons
Dr. Frank Ogston[192] has recommended sulphide of ammonium to be added
to any liquid as a test for chloral. The contents of the stomach are
filtered or submitted to dialysis, and the test applied direct. If
chloral is present, there is first an orange-yellow colour; on standing,
the fluid becomes more and more brown, then troubled, an amorphous
precipitate falls to the bottom, and a peculiar odour is developed. With
10 mgrms. of chloral in 1 c.c. of water, there is an evident
precipitate, and the odour can readily be perceived; with 1 mgrm.
dissolved in 1 c.c. of water, there is an orange-yellow colour, and also
the odour, but no precipitate; with ·1 mgrm. in 1 c.c. of water, there
is a weak, pale, straw-yellow colour, which can scarcely be called
characteristic. The only substance giving in neutral solutions the same
reactions is antimony; but, on the addition of a few drops of acid, the
antimony falls as an orange-yellow precipitate, while, if chloral alone
is present, there is a light white precipitate of sulphur.
[192] _Vierteljahrsschrift f. gerichtl. Medicin_, 1879, Bd. xxx. Hft. 1,
S. 268.
VIII.--Bisulphide of Carbon.
§ 208. Bisulphide of carbon--_carbon disulphide_, _carbon sulphide_
(CS₂)--is a colourless, volatile fluid, strongly refracting light.
Commercial samples have a most repulsive and penetrating odour, but
chemically pure carbon sulphide has a smell which is not disagreeable.
The boiling-point is 47°; the specific gravity at 0° is 1·293. It is
very inflammable, burning with a blue flame, and evolving sulphur
dioxide; is little soluble in water, but mixes easily with alcohol or
ether. Bisulphide of carbon, on account of its solvent powers for
sulphur, phosphorus, oils, resins, caoutchouc, gutta-percha, &c., is in
great request in certain industries. It is also utilised for
disinfecting purposes, the liquid being burnt in a lamp.
§ 209. =Poisoning by Carbon Bisulphide.=--In spite of the cheapness and
numerous applications of this liquid, poisoning is very rare. There
appears to be a case on record of attempted self-destruction by this
agent, in which a man took 2 ozs. (56·7 c.c.) of the liquid, but without
a fatal result. The symptoms in this case were pallor of the face, wide
pupils, frequent and weak pulse, lessened bodily temperature, and
spasmodic convulsions. Carbon disulphide was detected in the breath by
leading the expired air through an alcoholic solution of
triethyl-phosphin, with which it struck a red colour. It could also be
found in the urine in the same way. An intense burning in the throat,
giddiness, and headache lasted for several days.
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