Poisons, Their Effects and Detection: A Manual for the Use of Analytical Chemists and ExpertsBlyth, Alexander Wynter
Science
Poisons, Their Effects and Detection: A Manual for the Use of Analytical Chemists and Experts
Blyth, Alexander Wynter
Poisons
Dinitro-Bands.
In Red. In Green.
-----/\-----
50-52 62-66 70-77
After NH₄SO₄, 53-55 62-66 70-77
„ NH₃, 54-58 60-65 70-77
„ NH₄SO₄ + NH₃, 52-55 60-65 70-77
Taking the symptoms as a whole, there has been noted:--a blue colour of
the lips, not unfrequently extending over the whole face, and even the
conjunctivæ have been of a marked blue colour, giving the sufferer a
strange livid appearance. In other cases there have been jaundice, the
conjunctivæ and the skin generally being yellow, the lips blue.
Occasionally gastric symptoms are present. Sleeplessness is common, and
not unfrequently there is some want of muscular co-ordination, and the
man staggers as if drunk. In more than one case there has been noticed
sudden delirium. There is in chronic cases always more or less anæmia,
and the urine is remarkable in its colour, which ranges from a slightly
dark hue up to positive blackness. In a large proportion of cases there
is ophthalmic trouble, the characteristics of which (according to Mr.
Snell) are “failure of sight, often to a considerable degree, in a more
or less equal extent on the two sides; concentric attraction of visual
field with, in many cases, a central colour scotoma; enlargement of
retinal vessels, especially the veins; some blurring, never extensive,
of edges of disc, and a varying degree of pallor of its surface--the
condition of retinal vessels spoken of being observed in workers with
the dinitro-benzol, independently of complaints of defective sight.
Cessation of work leads to recovery.”
§ 250. =Detection of Dinitro-benzol.=--Dinitro-benzol may be detected in
urine, in blood, and in fluids generally, by the following
process:--Place tinfoil in the fluid, and add hydrochloric acid to
strong acidity, after allowing the hydrogen to be developed for at least
an hour, make the fluid alkaline by caustic soda, and extract with ether
in a separating tube; any metaphenylene-diamine will be contained in the
ether; remove the ether into a flask, and distil it off; dissolve the
residue in a little water.
Acidify a solution of sodium nitrite with dilute sulphuric acid; on
adding the solution, if it contains metaphenylene-diamine, a yellow to
red colour will be produced, from the formation of Bismarck brown
(triamido-phenol).
XII.--Hydrocyanic Acid.
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