Political and commercial geology and the world's mineral resources
Science
Political and commercial geology and the world's mineral resources
Geology, Economic; Mines and mineral resources
For purposes of geologic study, deposits of manganese oxides may be
considered in two groups, as follows: (1) those derived from more or
less localized masses of carbonate or silicate materials, generally
with more than 5 per cent. manganese, that seem to have no relation to
the surface of the earth; and (2) those originally deposited near the
surface as localized bodies of oxides.
Under the first group are zones of carbonate or silicate rocks in
contact with intrusive igneous rocks, such as are found in Brazil and
India. These zones contain manganiferous carbonates (mixed with iron,
lime, and magnesia); and silicates (spessartite or manganese garnet and
piedmontite or manganese epidote and possibly rhodonite, or manganese
pyroxene). By the weathering of such rocks, large bodies of high-grade
oxides have been formed.
Manganese also occurs in fissure veins or the adjacent wall rocks in
regions that have been intruded by igneous rocks. The veins commonly
contain rhodochrosite, manganiferous siderite, or rhodonite, associated
with quartz and metallic sulphide minerals, including alabandite, the
sulphide of manganese. Such veins are known in Philipsburg and Butte,
Mont.; Silverton, Colo., and elsewhere. In such regions if the wall
rocks adjacent to fissures are limestone or dolomite, they may be
extensively replaced by manganiferous siderite or other carbonates
which on weathering yield large bodies of manganese oxides, locally
mixed with iron oxides. Such bodies are known at Leadville, Colo.
The manganese existing in sediments, notably clayey, but in part
carbonate, may migrate locally after the sediments are slightly buried
and form zones of manganiferous carbonate and silicate concretions
parallel to the bedding. Where, as in the Batesville district,
Arkansas, these zones are exposed by erosion, the manganese is further
concentrated as masses of oxides in residual clay.
Metamorphic rocks, such as slates and schists, here and there, as in
Spain, Newfoundland, California, and Washington, contain extensive
lenses of rhodonite or other silicate with or without rhodochrosite,
roughly parallel to the bedding. The origin of these lenses, which are
generally rather remote from igneous intrusions, is obscure. Some are
considered to be materials laid down during sedimentation, others are
thought to represent concentrations effected during metamorphism when
the sediments were deeply buried.
In the second group mentioned above (manganese deposits first
concentrated near the surface as oxides) are included extensive
deposits of oxides interbedded with marine sediments, as in the
Caucasus region, Russia. Others interbedded with volcanic material,
tuffs and flows, are known in the Mediterranean region and in Chile. In
India important beds of oxides are interbedded with quartzite and slate.
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