Political and commercial geology and the world's mineral resources
Science
Political and commercial geology and the world's mineral resources
Geology, Economic; Mines and mineral resources
White antimony oxide, mainly the tetraoxide (Sb₂O₄), is used for
making opaque white enamel and other sanitary ware. In this use
antimony oxides compete with tin oxide. Antimony oxide, mainly
trioxide, is used as a coloring agent in the manufacture of glass,
as it is more readily fusible than tetraoxide and does not impart
opacity to the glass. Antimony oxides are further used as paint
pigments.
The red sulphides of antimony are used in vulcanizing and coloring
red rubber and also as paint pigments. The natural antimony
trisulphide, stibnite, enters into the composition of safety matches
or of the compound that is put on the match box.
Antimonate of lead containing an excess of lead oxide, known as
“Naples yellow,” is used in oil paints and in the glass and ceramic
industries. The antimony salt, tartar emetic (double tartrate of
antimony and potassium), and antimony fluoride are employed as
mordants in dyeing. Tartar emetic and antimony trioxide are employed
medicinally.
War uses.--Antimonial lead carrying 12 to 13 per cent. of antimony is
employed in the manufacture of shrapnel bullets. Smaller quantities
of liquated antimony sulphide are used in the primers of shells. For
this last purpose it is claimed the material must carry less than 2
per cent. of impurities insoluble in hydrochloric acid. Antimony
sulphide as a powder is used in the charge of some shells to produce
on explosion a white smoke which is of service in range finding.
During the war Germany used antimony to some extent as a substitute for
more important metals in the manufacture of currency, but shortage of
antimony itself did not allow this use to become important.
GEOLOGICAL DISTRIBUTION
The geological distribution of commercial antimony depends, with a
few exceptions, upon the distribution of the principal ore mineral,
stibnite (antimony sulphide). Cervantite, sernarmontite and valentinite
are antimony oxides resulting directly from the decomposition of
stibnite near the surface, and with other oxidized products form the
chief ores of certain districts. Metallic antimony, also a result of
oxidation of the sulphides, is rarely found, and still more rarely is
it an ore mineral. Jamesonite, the sulphide of antimony and lead, is of
frequent occurrence and is the principal ore of one important deposit
in Mexico. Antimony is also recovered from the refining of antimonial
lead.
Stibnite occurs in quartz veins and related deposits. Many of the
important antimony deposits of the world occur in more or less close
genetic relationship with eruptives of Tertiary age. The ore often
gives way to pyrite with depth. A few important deposits occur in
connection with intrusive rocks formed at considerable depth and are
probably of contact metamorphic origin.
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