Political and commercial geology and the world's mineral resources
Science
Political and commercial geology and the world's mineral resources
Geology, Economic; Mines and mineral resources
During the past few years Dr. C. M. Johnson has succeeded in
manufacturing laboratory ware made from zirconium minerals mixed with
other refractories. Filtering crucibles, muffles, combustion tubes
and boats, pyrometer protection tubes, and Kipp generators are now
on the market, competing in price with German porcelain and fused
silica. Zirconia crucibles are made from the fused material ground
in a suitable mill. The powder is pressed or molded into shape with
an organic binder, such as starch, or perhaps, better still, with a
plastic cement made by grinding the fused material to 20 mesh, when
it becomes colloidal in the presence of water. After drying, the
articles are burned at a very high temperature (2300 to 2400°C.) until
contraction ceases.
Fused zirconia has a high thermal endurance; is not affected when
heated to redness and plunged into cold water, its coefficient of
expansion being as low as 0.00000084; and its resistance to crushing
is many times that of quartz glass. Its hardness is between that of
corundum and quartz; its specific gravity 5.89, and porosity below
1 per cent. Its melting point is 2950°C, but 0.5 per cent. impurity
reduces that by 100°C. Platinum, with a melting point of about 1750°C.,
can be melted to a mobile liquid in zirconia crucibles, and it is
claimed that the boiling point of pure iron has been determined in
similar crucibles.
Chemically, zirconia is very inert, being highly resistant to acids,
fused alkalies, fused quartz, or molten glass. Possibly no other
material known to chemists possesses such a combination of desirable
refractory properties. Its one undesirable characteristic is its
tendency under certain conditions at high temperatures, in the presence
of nitrogen or carbon, to become converted into nitride or carbide.
An instructive paper entitled “Zirconia as a Refractory,” by E. H.
Rodd, was published in the Journal of the Society of Chemical Industry,
June 15, 1918.
Public-domain text, read in full here on John Shaqi.
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