If properties of the thermal condition varying greatly from the tensions
of gases had been chosen, this relation would have assumed very
complicated forms, and the agreement between heat and the other energies
above considered would not subsist. It is very instructive to reflect
upon this point. A _natural law_, therefore, is not implied in the
conformity of the behavior of the energies, but this conformity is
rather conditioned by the uniformity of our modes of conception and is
also partly a matter of good fortune.
VI. THE DIFFERENCES OF THE ENERGIES AND THE LIMITS OF THE PRINCIPLE OF
ENERGY.
Of every quantity of heat _Q_ which does work in a reversible process
(one unaccompanied by loss) between the absolute temperatures _T₁_,
_T₂_, only the portion
_(T₁-T₂)/T₁_
is transformed into work, while the remainder is transferred to the
lower temperature-level _T₂_. This transferred portion can, upon the
reversal of the process, with the same expenditure of work, again be
brought back to the level _T₁_. But if the process is not reversible,
then more heat than in the foregoing case flows to the lower level, and
the surplus can no longer be brought back to the higher level _T₂_
without some _special_ expenditure. W. Thomson (1852), accordingly, drew
attention to the fact, that in all non-reversible, that is, in all real
thermal processes, quantities of heat are lost for mechanical work, and
that accordingly a dissipation or waste of mechanical energy is taking
place. In all cases, heat is only partially transformed into work, but
frequently work is wholly transformed into heat. Hence, a tendency
exists towards a diminution of the _mechanical_ energy and towards an
increase of the _thermal_ energy of the world.
For a simple, closed cyclical process, accompanied by no loss, in which
the quantity of heat _Q₁_ is taken from the level _T₁_, and the quantity
_Q₂_ is deposited upon the level _T₂_, the following relation, agreeably
to equation (2), exists,
_-(Q₁/T₁) + (Q₂/T₂) = 0_.
Similarly, for any number of compound reversible cycles Clausius finds
the algebraical sum
_[sum]Q/T = 0_,
and supposing the temperature to change continuously,
_[integral]dQ/T = 0_ (4)
Here the elements of the quantities of heat deducted from a given level
are reckoned negative, and the elements imparted to it, positive. If the
process is not reversible, then expression (4), which Clausius calls
_entropy_, increases. In actual practice this is always the case, and
Clausius finds himself led to the statement:
1. That the energy of the world remains constant.
2. That the entropy of the world tends toward a maximum.
Once we have noted the above-indicated conformity in the behavior of
different energies, the _peculiarity_ of thermal energy here mentioned
must strike us. Whence is this peculiarity derived, for, generally every
energy passes only partly into another form, which is also true of
thermal energy? The explanation will be found in the following.
Public-domain text, read in full here on John Shaqi.
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